Bimetallic complexes with porphyrins containing a cyclometalated phenylpyridine group

被引：4

作者：

Cheung, KM ^{[1
]}

Zhang, QF ^{[1
]}

Mak, WL ^{[1
]}

Sung, HHY ^{[1
]}

Williams, ID ^{[1
]}

Leung, WH ^{[1
]}

机构：

[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 02期

关键词：

bimetallic; cyclometalated; porphyrin; nickel; palladium; iridium;

D O I：

10.1016/j.jorganchem.2004.09.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of Ni(HP1) (H3P1 = meso-5-[4'-(2"-pyridyl)phenyl]-10,15,20-triphenyporphyrin) with K-2[PdCl4] in EtOH afforded [Pd{Ni(P-1)}](2)(mu-Cl)(2) that reacted with NaS2CNEt2 to give Pd(S2CNEt2)[Ni(P-1)]. Reaction of Ni(HP1) with [Ir(H)(2)(PPh3)(2)(Me-2-CO)(2)][BF4] afforded Ir(H)Cl(PPh3)(2)[Ni(P-1)]. The crystal structures of Pd(S2CNEt2)[Ni(P-1)] and Ir(H)(Cl)(PPh3)(2)[Ni(P-1)] have been determined. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：253 / 260

页数：8

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