Structure determination of unsolvated potassium, rubidium, and cesium carbazolates

被引：13
作者：
Dinnebier, Robert
Esbak, Hoda
Olbrich, Falk
Behrens, Ulrich
机构：
[1] Univ Hamburg, Inst Anorgan & Angew Chem, D-20146 Hamburg, Germany
[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
来源：
ORGANOMETALLICS | 2007年 / 26卷 / 10期
关键词：
D O I：
10.1021/om060927t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solid-state structures of unsolvated potassium, rubidium, and cesium carbazolates were determined using laboratory X-ray powder diffraction data. Potassium and rubidium carbazolates adopt a polymeric helical arrangement, whereas cesium carbazolate forms a polymeric twisted column structure.
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页码：2604 / 2608
页数：5
相关论文
共 56 条
[1]   Ion pair properties of lithium and cesium salts of carbazole [J].
Abbotto, A ;
Streitwieser, A ;
Stratakis, M ;
Krom, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (08) :1718-1723
[2]  
Allen F.H., 1993, CHEM AUTOMAT NEWS, V8, P31
[3]  
[Anonymous], 1990, ANGEW CHEM, V102, P1179
[4]   Synthesis and structures of alkali metal amides derived from the ligands [N(SiMe2Ph)(SiMe3)]-, [N(tBu)(SiMe3)]-, [N(Ph)(2-C5H4N)]- and [N(2-C5H4N)2]- [J].
Antolini, F ;
Hitchcock, PB ;
Khvostov, AV ;
Lappert, MF .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) :3391-3400
[5]   Structural studies of the chiral lithium amides [{PhC(H)Me}2NLi] and [PhCH2{PhC(H)Me}NLi•THF] derived from α-methylbenzylamine [J].
Armstrong, DR ;
Henderson, KW ;
Kennedy, AR ;
Kerr, WJ ;
Mair, FS ;
Moir, JH ;
Moran, PH ;
Snaith, R .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (22) :4063-4068
[6]   SYNTHESES AND SOLID-STATE STRUCTURES OF TRIMERIC DIBENZYLAMIDOLITHIUM AND ITS DIETHYL-ETHER AND HEXAMETHYLPHOSPHORAMIDE DIMERIC COMPLEXES - AN EXPLANATION OF THESE STRUCTURES AND EVIDENCE FOR LI...CH INTERACTIONS IN BOTH SOLID AND SOLUTION PHASES [J].
ARMSTRONG, DR ;
MULVEY, RE ;
WALKER, GT ;
BARR, D ;
SNAITH, R ;
CLEGG, W ;
REED, D .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (03) :617-628
[7]   CRYSTAL-STRUCTURE OF LITHIUM DIISOPROPYLAMIDE (LDA) - AN INFINITE HELICAL ARRANGEMENT COMPOSED OF NEAR-LINEAR N-LI-N UNITS WITH 4 UNITS PER TURN OF HELIX [J].
BARNETT, NDR ;
MULVEY, RE ;
CLEGG, W ;
ONEIL, PA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (21) :8187-8188
[8]  
BARR D, 1989, ANGEW CHEM INT EDIT, V28, P1241
[9]   TRIMERIC DIBENZYLAMIDOLITHIUM AND ITS DIMERIC DIETHYL-ETHER AND HEXAMETHYLPHOSPHORAMIDE COMPLEXES - STRUCTURAL AND THEORETICAL-STUDIES OF REACTIVE ORGANONITROGEN LITHIUM OLIGOMERS [J].
BARR, D ;
CLEGG, W ;
MULVEY, RE ;
SNAITH, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (05) :285-287
[10]  
BARR D, 1989, ANGEW CHEM, V101, P1279
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