μ-Succinato-bis[aqua(2,2′:6′,2"-terpyridine)copper(II)] dinitrate dihydrate

被引:1
|
作者
Mei, Chongzhen [1 ]
Lei, Qingduo [1 ]
Zhang, Peng [1 ]
机构
[1] N China Univ Water Conservancy & Elect Power, Inst Environm & Municipal Engn, Zhengzhou 450011, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词
SUCCINATE; CRYSTAL;
D O I
10.1107/S1600536810006811
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Cu-2(C4H4O4)(C15H11N3)(2)(H2O)(2)](NO3)(2)center dot 2H(2)O, was synthesized under hydrothermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu-II ion is pentacoordinated in a tetragonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2 ''-terpyridine ligand occupying the basal plane, and a water O atom located at the apical site. In the crystal structure, O-H center dot center dot center dot O hydrogen bonding links the molecules into a chain parallel to the a axis.
引用
收藏
页码:M346 / U3960
页数:12
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