Spin-orbit effects in metal-metal multiple bonded M2X8 halide complexes

被引：0

作者：

Hernández-Acevedo, L ^{[1
]}

Arrata-Pérez, R ^{[1
]}

机构：

[1] Univ Andres Bello, Fac Ecol & Recursos Nat, Dept Ciencias Quim, Santiago, Chile

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2004年 / 49卷 / 04期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dirac molecular spinor calculations on the Re2Cl82-, Re2Br82-, Os2Cl82- (both staggered and eclipsed isomers), Os-2 Br-8(2-) and Os2I82- cluster ions are reported. Here we report the calculations of the spin-orbit splitting affecting the metal and ligand core-like states and also affecting the pi and delta metal-metal bonds. We also compare the calculated molecular spin-orbit splitting against the calculated atomic spin-orbit splitting, and, against available experimental data.

引用

页码：361 / 365

页数：5

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