Synthesis of New Quinoline-Conjugated Calixarene as a Fluorescent Sensor for Selective Determination of Cu2+ Ion

被引：13

作者：

Sayin, Serkan ^{[1
]}

机构：

[1] Giresun Univ, Fac Engn, Dept Environm Engn, TR-28200 Giresun, Turkey

来源：

JOURNAL OF FLUORESCENCE | 2021年 / 31卷 / 04期

关键词：

Calixarene; Synthesis; Quinoline; Sensor; Copper (II); Fluorescence quenching; PROBE; EFFICIENT; COMPLEX;

D O I：

10.1007/s10895-021-02749-6

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A novel quinoline-functionalized calix [4] arene derivative (Quin-Calix) has been successfully synthesized at partial cone conformation and duly characterized by using FTIR, H-1-NMR, C-13-NMR, ESI-MS and elemental analysis techniques. Moreover, the cation-binding property of the calix [4] arene derivative (Quin-Calix) has been investigated towards Cu2+, Ba2+, Cd2+, Co2+, Ni2+, Zn2+ and Fe3+ ions, and the recognition event monitored by UV-Vis absorption and fluorescence studies. The results indicated that Quin-Calix displays a remarkable affinity and selectivity only for Cu2+ ion. The binding constant and stoichiometry of the complex formed between Quin-Calix and Cu2+ ion have been also calculated from the fluorescence data. In addition, Stern-Vohmer equation has been used to elucidate the mechanism of quenching.

引用

页码：1143 / 1151

页数：9

共 37 条

[1] Synthesis of Calix(aza)crown and its Oligomeric Analogue for the Extraction of Selected Metal Cations and Dichromate Anions [J].

Akkus, Guelderen Uysal ;

Memon, Shahabuddin ;

Sezgin, Mehmet ;

Yilmaz, Mustafa .

CLEAN-SOIL AIR WATER, 2009, 37 (02) :109-114

[2] Ion sensing of sister sensors based-on calix[4]arene in aqueous medium and their bioimaging applications [J].

Alizada, Malak ;

Gul, Alev ;

Oguz, Mehmet ;

Kursunlu, Ahmed Nuri ;

Yilmaz, Mustafa .

DYES AND PIGMENTS, 2021, 184

[3]

[Anonymous], 2016, CALIXARENES

[4] Multivalent and Multifunctional Calixarenes in Bionanotechnology [J].

Baldini, Laura ;

Casnati, Alessandro ;

Sansone, Francesco .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 2020 (32) :5056-5069

[5] Luminescent Eu(III) hybrid sensors for in situ copper detection [J].

Barja, Beatriz C. ;

Bari, Sara E. ;

Claudia Marchi, M. ;

Iglesias, Fabricio L. ;

Bernardi, Milagros .

SENSORS AND ACTUATORS B-CHEMICAL, 2011, 158 (01) :214-222

[6] Selective recognition by novel calix system: ICT based chemosensor for metal ions [J].

Bhatt, Keyur D. ;

Makwana, Bharat A. ;

Vyas, Disha J. ;

Mishra, Divya R. ;

Jain, Vinod K. .

JOURNAL OF LUMINESCENCE, 2014, 146 :450-457

[7] Dual Fluorescence Response of Newly Synthesized Naphthalene Appended Calix[4]arene Derivative towards Cu2+ and I- [J].

Bhatti, Asif Ali ;

Oguz, Mehmet ;

Memon, Shahabuddin ;

Yilmaz, Mustafa .

JOURNAL OF FLUORESCENCE, 2017, 27 (01) :263-270

[8] Convenient direct synthesis of bisformylated calix[4]arenes via ipso substitution [J].

Chawla, H. M. ;

Pant, N. ;

Srivastava, Bindu ;

Upreti, Shailesh .

ORGANIC LETTERS, 2006, 8 (11) :2237-2240

[9] A ratiometric and far-red fluorescence "off-on" sensor for sequential determination of copper(II) and L-histidine based on FRET system between N-acetyl-L-cysteine-capped AuNCs and N,S,P co-doped carbon dots [J].

Don, Wenjuan ;

Wang, Ruiping ;

Gon, Xiaojuan ;

Liang, Wenting ;

Fan, Li ;

Son, Shengmei ;

Dong, Chuan .

MICROCHIMICA ACTA, 2020, 187 (05)

[10] Fluorescent gold clusters as nanosensors for copper ions in live cells [J].

Durgadas, C. V. ;

Sharma, C. P. ;

Sreenivasan, K. .

ANALYST, 2011, 136 (05) :933-940

← 1 2 3 4 →