Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds

被引：12

作者：

Takaya, Jun ^{[1
,2
]}

Hoshino, Mayuko ^{[1
]}

Ueki, Kanako ^{[1
]}

Saito, Narumasa ^{[1
]}

Iwasawa, Nobuharu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[2] JST, PRESTO, Honcho, Kawaguchi, Saitama 3320012, Japan

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 39期

基金：

日本学术振兴会;

关键词：

DEHYDROGENATION; BEARING; NICKEL; CO2; ACTIVATION; CHEMISTRY; CATALYSIS; LIGANDS; BORON;

D O I：

10.1039/c9dt03443a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural analyses of pincer-type iridium complexes having gallyl- and indyl-metalloligands were achieved utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds. A BH3-coordinated PInP-Ir dihydride complex was also developed as an equivalent to an iridium dihydride complex, which could be a useful catalyst for synthetic reactions.

引用

页码：14606 / 14610

页数：5

共 34 条

[1] σ-Acceptor, Z-type ligands for transition metals [J].

Amgoune, Abderrahmane ;

Bourissou, Didier .

CHEMICAL COMMUNICATIONS, 2011, 47 (03) :859-871

[2] Complexes of ambiphilic ligands: reactivity and catalytic applications [J].

Bouhadir, Ghenwa ;

Bourissou, Didier .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (04) :1065-1079

[3] A Bimetallic Nickel-Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride [J].

Cammarota, Ryan C. ;

Vollmer, Matthew V. ;

Xie, Jing ;

Ye, Jingyun ;

Linehan, John C. ;

Burgess, Samantha K. ;

Appel, Aaron M. ;

Gagliardi, Laura ;

Lu, Connie C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (40) :14244-14250

[4] Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation [J].

Cammarota, Ryan C. ;

Lu, Connie C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (39) :12486-12489

[5] Dehydrogenation and Related Reactions Catalyzed by Iridium Pincer Complexes [J].

Choi, Jongwook ;

MacArthur, Amy H. Roy ;

Brookhart, Maurice ;

Goldman, Alan S. .

CHEMICAL REVIEWS, 2011, 111 (03) :1761-1779

[6] Covalent radii revisited [J].

Cordero, Beatriz ;

Gomez, Veronica ;

Platero-Prats, Ana E. ;

Reves, Marc ;

Echeverria, Jorge ;

Cremades, Eduard ;

Barragan, Flavia ;

Alvarez, Santiago .

DALTON TRANSACTIONS, 2008, (21) :2832-2838

[7] Synthesis and Platinum Complexes of an Alane-Appended 1,1′-Bis(phosphino)ferrocene Ligand [J].

Cowie, Bradley E. ;

Tsao, Fu An ;

Emslie, David J. H. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (07) :2165-2169

[8] Efficient catalysis of ammonia borane dehydrogenation [J].

Denney, Melanie C. ;

Pons, Vincent ;

Hebden, Travis J. ;

Heinekey, D. Michael ;

Goldberg, Karen I. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (37) :12048-12049

[9] Original Transition Metal→Indium Interactions upon Coordination of a Triphosphine-Indane [J].

Derrah, Eric J. ;

Sircoglou, Marie ;

Mercy, Maxime ;

Ladeira, Sonia ;

Bouhadir, Ghenwa ;

Miqueu, Karinne ;

Maron, Laurent ;

Bourissou, Didier .

ORGANOMETALLICS, 2011, 30 (04) :657-660

[10] A Significant but Constrained Geometry Pt→Al Interaction: Fixation of CO2 and CS2, Activation of H2 and PhCONH2 [J].

Devillard, Marc ;

Declercq, Richard ;

Nicolas, Emmanuel ;

Ehlers, Andreas W. ;

Backs, Jana ;

Saffon-Merceron, Nathalie ;

Bouhadir, Ghenwa ;

Slootweg, J. Chris ;

Uhl, Werner ;

Bourissou, Didier .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (14) :4917-4926

← 1 2 3 4 →