Synthesis of continuous substitutional solid solutions M1-x Ni x (H2PO4)2•2H2O with M = Mg, Mn, Co, or Zn

被引：7
作者：
Viter, V. N.
Nagornyi, P. G.
机构：
[1] Natl Acad Sci Ukraine, Vernadsky Inst Gen & Inorgan Chem, UA-252143 Kiev, Ukraine
[2] Natl Taras Shevchenko Univ Kiev, UA-252017 Kiev, Ukraine
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 01期
关键词：
D O I：
10.1134/S0036023607010044
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New continuous substitutional solid solutions Mg1-xNix(H2PO4)(2) center dot 2H(2)O, Mn1-xNix (H2PO4)(2) center dot 2H(2)O, Co1-xNix(H2PO4)(2) center dot 2H(2)O, and Zn1-xNi (x)(H2PO4)(2) center dot 2H(2)O (0 <= x <= 1.00) crystallizing in monoclinic space group P2(1)/n have been synthesized. Their end-member is Ni(H2PO4)(2) center dot 2H(2)O. Ni(H2PO4)(2) center dot 2H(2)O is isostructural to magnesium, manganese, iron, cobalt, zinc, and cadmium dihydrogenphosphates. The chemical composition and the unit cell parameters have been determined for the solid solutions. Their IR spectra have been measured.
引用
收藏
页码：14 / 20
页数：7
相关论文
共 20 条
  • [1] [Anonymous], 1981, ATLAS INFRAKRASNYH S
  • [2] [Anonymous], ANAL CHEM COBALT
  • [3] Antraptseva NM, 1993, ZH NEORG KHIM+, V38, P1595
  • [4] ANTRAPTSEVA NM, 1988, ZH NEORG KHIM+, V33, P2495
  • [5] AVERBUCHPOUCHOT MT, 1973, B SOC FR MINERAL CR, V96, P278
  • [6] Charlot G., 1961, METHODES CHIMIE ANAL
  • [7] GUSE W, 1985, NEUES JB MINER MONAT, P433
  • [8] HINSCH TR, 1985, NEUES JB MINER MONAT, P439
  • [9] *IZD VO STAND, 1986, GOST 20851 75 MIN FE
  • [10] MORACHEVSKII YV, 1960, ANAL KHIM, V15, P656
12