Preparation and dielectric properties of polyarylene ether nitriles/TiO2 nanocomposite film

被引:56
作者
Li, C
Tang, AB
Zou, YB
Liu, XB [1 ]
机构
[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
[2] Sichuan Dongfang Insulating Mat Co Ltd, Mianyang 621000, Peoples R China
基金
中国国家自然科学基金;
关键词
polyarylene ether nitriles; nanocomposite; titanium oxide; dielectric property;
D O I
10.1016/j.matlet.2004.09.016
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polyarylene ether nitriles (PENs)/TiO2 nanocomposite has been successfully synthesized through the sol-gel process; the films were characterized by FTIR, XPS, SEM and TG. The dielectric properties of the films were also measured to find that the dielectric constant of nanocomposite films increases linearly with the TiO2 weight content and reaches 6.21 at a 20 wt.% TiO2 content. The nanocomposite films have favorable mechanical and thermal properties and are not sacrificing dielectric breakdown strength compared to that of pristine polymer. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 63
页数:5
相关论文
共 14 条
  • [1] Bedri E., 2001, LANGMUIR, V17, P2664
  • [2] BENJARAM MR, 2001, LANGMUIR, V17, P1132
  • [3] Next generation integral passives: materials, processes, and integration of resistors and capacitors on PWB substrates
    Bhattacharya, SK
    Tummala, RR
    [J]. JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2000, 11 (03) : 253 - 268
  • [4] The synthesis and morphology characteristic study of BAO-ODPA polyimide/TiO2 nano hybrid films
    Chiang, PC
    Whang, WT
    [J]. POLYMER, 2003, 44 (08) : 2249 - 2254
  • [5] Nano-composite TiO2-PI via sol-gel process
    He, YQ
    Ping, YH
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2003, 78 (03) : 614 - 619
  • [6] In situ formation of nanosized TiO2 domains within poly(amide-imide) by a sol-gel process
    Hu, Q
    Marand, E
    [J]. POLYMER, 1999, 40 (17) : 4833 - 4843
  • [7] High refractive-index thin films prepared from trialkoxysilane-capped poly(methyl methacrylate)-titania materials
    Lee, LH
    Chen, WC
    [J]. CHEMISTRY OF MATERIALS, 2001, 13 (03) : 1137 - 1142
  • [8] Photosensitive polyimide (PSPI) materials containing inorganic nano particles (I)PSPL/TiO2 hybrid materials by sol-gel process
    Li, L
    Lu, QH
    Yin, J
    Qian, XF
    Wang, WK
    Zhu, ZK
    Wang, ZG
    [J]. MATERIALS CHEMISTRY AND PHYSICS, 2002, 74 (02) : 210 - 213
  • [9] Dielectric properties of polymer/ferroelectric ceramic composites from 100 Hz to 10 GHz
    Popielarz, R
    Chiang, CK
    Nozaki, R
    Obrzut, J
    [J]. MACROMOLECULES, 2001, 34 (17) : 5910 - 5915
  • [10] Saxena A, 2003, POLYM BULL, V50, P219