Selective reduction of nitro-compounds to primary amines by tetrapyridinoporphyrazinato zinc (II) supported on DFNS

被引：3
作者：
Kiani, Zahra [1 ]
Zhiani, Rahele [2 ,3 ]
Khosroyar, Susan [4 ]
Motavalizadehkakhky, Alireza [2 ]
Hosseiny, Malihesadat [2 ]
机构：
[1] Islamic Azad Univ, Neyshabur Branch, Dept Chem Engn, Fac Sci, Neyshabur, Iran
[2] Islamic Azad Univ, Neyshabur Branch, Dept Chem, Fac Sci, Neyshabur, Iran
[3] Islamic Azad Univ, Neyshabur Branch, Dept Chem, New Mat Technol & Proc Res Ctr, Neyshabur, Iran
[4] Islamic Azad Univ, Quchan Branch, Dept Chem Engn, Quchan, Iran
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 130卷
关键词：
Nanocatalyst; Green chemistry; DFNS; Zinc; One-pot synthesis; CARBON-DIOXIDE; REUSABLE CATALYST; NITRO-COMPOUNDS; BIGINELLI-TYPE; IONIC LIQUID; NANOPARTICLES; EFFICIENT; KCC-1; 3-ARYL-2-OXAZOLIDINONES; HYDROGENATION;
D O I：
10.1016/j.inoche.2021.108696
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Here, we created and synthesized a heterogeneous catalyst from porphyrazinatozinc (tmtppa-Zn) supported on DFNS (tmtppa-Zn/DFNS). This is a simple method for hydrogenation of nitro-compounds and their conversion to primary amines without producing toxic by-products. These reactions take place under mild reaction situations. The catalyst system was comfortably retrieved and reutilized in at least ten runs without the reduction of catalytic activity.
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页数：11
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