Comparison of electrical and electrochemical properties between poly(vinyl chloride) and poly(vinyl methylaniline) composites with polyaniline

被引:0
作者
Park, YH [1 ]
Yang, KY [1 ]
机构
[1] Sungkyunkwan Univ, Sch Appl Chem & Chem Engn, Suwon 440746, South Korea
关键词
electrochemical polymerization; polyaniline; poly(vinyl chloride); poly(vinyl methylaniline);
D O I
10.1080/15421400490506856
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The -modifiud PVC with 1),bulky functional groups, namely poly(vinyl methylaniline) (PVMA) was synthesized, and the PVMA/Polyaniline (PANO composite was prepared electrochemically to compare its electrical and electrochemical properties with those of PVC/PANI composite. The synthesized PVMA, 14 was chain characterized using FT-IR mid H-1-NMR spectroscopy. To prepare composite., PVC and PVMA were spin-coated on a Pt disc electrode. After the pre-coated films were swelled in DMF/water mixture 1.0 M sulfuric acid, the electrochemical polymeruzation PANI on PVC or- PVMA coated Pt electrode was performed by the costant-potential and, potenyial-cyclic method, respectively Vie conductivity, cyclic voltammetry, and chronamperometry of PVMA/PANI composite were investigated. comparing with, those PVC/PANI composite.
引用
收藏
页码:501 / 507
页数:7
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