Electrochemical and mechanical behavior of carbon composite bipolar plate for fuel cell

被引:118
作者
Kakati, B. K. [1 ]
Sathiyamoorthy, D. [2 ]
Verma, A. [1 ]
机构
[1] Indian Inst Technol, Dept Chem Engn, Gauhati 781039, Assam, India
[2] BARC, Powder Met Div, Bombay 400705, Maharashtra, India
关键词
Bipolar plate; Corrosion; Cyclic voltammetry; Fuel cell; Phenolic resin; Reinforcements; FORMALDEHYDE RESIN/GRAPHITE COMPOSITE; PHOSPHORIC-ACID; GRAPHITE; CORROSION; POLYTETRAFLUOROETHYLENE; CONDUCTIVITY; IMPREGNATION; INJECTION; FILLERS; DESIGN;
D O I
10.1016/j.ijhydene.2010.02.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Composite bipolar plates for fuel cells were prepared by a compression molding technique using novolac type phenol formaldehyde resin as a binder and natural graphite, carbon black and carbon fiber as reinforcements. The plates were characterized for electrical conductivity, mechanical strength and corrosion resistance. The flexural strength of the bipolar plate for optimum composition (PF:30%; NG:60%; CB:5%; CF:5%) was 55.28 MPa, with a deflection of 5.2% at mid-span, while the in-plane and through-plane electrical conductivities were 286 and 92 S cm(-1), respectively. Corrosion analyses were conducted in normal and rigorous simulated polymer electrolyte membrane fuel cell and alkaline fuel cell environments. The corrosion current density was close to the limit set by the USA Department of Energy. The corrosion current density at the optimum composition was found to be 0.99 mu A cm(-2) for polymer electrolyte membrane fuel cell and 17.62 mu A cm(-2) for alkaline fuel cell environments. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:4185 / 4194
页数:10
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