A gem-organodizinc species assembled in a tetrameric cage

被引：44
作者：
Andrews, PC
Raston, CL [1 ]
Skelton, BW
White, AH
机构：
[1] Monash Univ, Dept Chem, Melbourne, Vic 3168, Australia
[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 05期
关键词：
D O I：
10.1021/om970986u
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].
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收藏
页码：779 / 782
页数：4
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