Pyridine-bridged bifunctional organocatalysts for the synthesis of cyclic carbonates from carbon dioxide

被引：5

作者：

Liu, Quan-Yao ^{[1
]}

Shi, Lei ^{[1
]}

Liu, Ning ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China

来源：

JOURNAL OF CHEMICAL RESEARCH | 2019年 / 43卷 / 7-8期

关键词：

carbon dioxide; cyclic carbonate; epoxide; hydrogen bond donor; organocatalysis; IONIC LIQUIDS; CO2; FIXATION; CATALYTIC CONVERSION; IMIDAZOLIUM BROMIDES; EPOXIDES; CYCLOADDITION; ACTIVATION; TRANSFORMATION; CAPTURE; MILD;

D O I：

10.1177/1747519819858710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hydroxyl- and carboxyl-functionalized imidazolium halides are used as efficient bifunctional organocatalysts for the synthesis of cyclic carbonates from CO2 and epoxides under mild reaction conditions. Control experiments suggest that the cycloaddition reaction is realized by the combination of the nucleophilic halide anions with hydroxyl and carboxyl groups as hydrogen bond donors. Moreover, the bifunctional organocatalysts can be easily recycled five times by simple filtration; however, a loss of activity was observed.

引用

页码：248 / 256

页数：9

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