Metal complex sensitizers in dye-sensitized solar cells

被引：473

作者：

Polo, AS ^{[1
]}

Itokazu, MK ^{[1
]}

Iha, NYM ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim, Lab Inorgan Photochem & Energy Convers, BR-05508900 Sao Paulo, Brazil

来源：

COORDINATION CHEMISTRY REVIEWS | 2004年 / 248卷 / 13-14期

基金：

巴西圣保罗研究基金会;

关键词：

dye-cells; sensitizers; dye-sensitized solar cells; natural dyes; energy conversion; photoelectrochemical solar cells;

D O I：

10.1016/j.ccr.2004.04.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A brief review of the investigation of solar energy conversion and the development of dye-sensitized thin-layer solar cells is presented, with the main focus on dyes, specially on d(6) metal complexes employed, since 1998, as photosensitizers of nanocrystalline semiconductors. An extensive literature coverage of the spectroscopic properties and the performance of solar cells employing a series of cis-[Ru(dcbH(2))(2)LL'] species, in which dcbH, is 4,4'-(CO2H)(2)-2,2'-bipyridine and L and/or L' are ancillary ligands, is presented along with non-carboxylic acid anchoring polypyridine-ruthenium complexes. The utilization of other d(6) metal complexes and natural extracts, with emphasis on Brazilian products, is also reviewed. A List of ligands with structures and a series of Tables summarize the collected data. The research and development on dye-sensitized solar cells conducted at our Laboratory of Inorganic Photochemistry and Energy Conversion at the University of Sao Paulo-Brazil is also covered in this context as a part of this special issue in homage to Prof. Gratzel. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1343 / 1361

页数：19

共 147 条

[1]

ALMEIDA MA, 1988, AN 6 S BRAS ELETROQU, P596

[2] Syntheses of mixed ligands complexes of Ru(II) with 4,4′-dicarboxy-2,2′-bipyridine and substituted pteridinedione and the use of these complexes in electrochemical photovoltaic cells [J].

Anandan, S ;

Latha, S ;

Maruthamuthu, P .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2002, 150 (1-3) :167-175

[3]

[Anonymous], 1981, PHOTOCHEMICAL CONVER, DOI DOI 10.1007/s00340-006-2293-z

[4]

ARAKAWA H, 2001, RECENT ADV RES DEV D

[5] Electrochemical and photoelectrochemical investigation of new carboxylatobipyridine (bis-bipyridine)ruthenium(II) complexes for dye-sensitized TiO2 electrodes [J].

Aranyos, V ;

Grennberg, H ;

Tingry, S ;

Lindquist, SE ;

Hagfeldt, A .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2000, 64 (02) :97-114

[6]

Aranyos V., 2003, J CHEM SOC DA, P1280

[7] ENHANCED SPECTRAL SENSITIVITY FROM RUTHENIUM(II) POLYPYRIDYL BASED PHOTOVOLTAIC DEVICES [J].

ARGAZZI, R ;

BIGNOZZI, CA ;

HEIMER, TA ;

CASTELLANO, FN ;

MEYER, GJ .

INORGANIC CHEMISTRY, 1994, 33 (25) :5741-5749

[8] Intramolecular energy transfer processes in binuclear Re-Os complexes [J].

Argazzi, R ;

Bertolasi, E ;

Chiorboli, C ;

Bignozzi, CA ;

Itokazu, MK ;

Iha, NYM .

INORGANIC CHEMISTRY, 2001, 40 (27) :6885-6891

[9]

Azzellini MAD, 1996, POLYHEDRON, V15, P4579

[10]

BALL P, 1997, MADE MEASURE NEW MAT

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