Novel tricyclic sesquiterpenes from Juniperus thurifera L chemical confirmation of the duprezianane skeleton

被引：22
作者：
Barrero, AF
AlvarezManzaneda, E
Lara, A
机构：
[1] Depto. de Quim. Orgánica, Facultad de Ciencias, Universidad de Granada
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 21期
关键词：
D O I：
10.1016/0040-4039(96)00640-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Three tricyclic sesquiterpenes, sesquithuriferol (1), alpha- (3) and beta-duprezianene (4) were isolated from the essential oil of the wood of Juniperus thurifera L. The structure and absolute configuration of 1 was established on the basis of 2D INADEQUATE and other 2D NMR spectra, as well as by chemical correlations. The structure of 3 and 4 were elucidated by 2D NMR spectra and confirmed by their synthesis from tosyl-solvolysis rearrangement of 1. Copyright (C) 1996 Elsevier Science Ltd
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页码：3757 / 3760
页数：4
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