Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond.: A kinetic study

被引：42
作者：
Baciocchi, E
Gerini, MF
Lanzalunga, O
机构：
[1] Univ Roma La Sapienza, Dipartimento Chim, I-00185 Rome, Italy
[2] Univ Roma La Sapienza, IMC, CNR, Sez Meccanismi Reaz, I-00185 Rome, Italy
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 25期
关键词：
D O I：
10.1021/jo048656o
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH3CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.
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页码：8963 / 8966
页数：4
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