Universal approach to quantum thermodynamics in the strong coupling regime

被引:46
作者
Dou, Wenjie [1 ]
Ochoa, Maicol A. [1 ,3 ,4 ]
Nitzan, Abraham [1 ,2 ]
Subotnik, Joseph E. [1 ]
机构
[1] Univ Penn, Dept Chem, Philadelphia, PA 19104 USA
[2] Tel Aviv Univ, Sackler Fac Sci, Sch Chem, IL-69978 Tel Aviv, Israel
[3] NIST, Ctr Nanoscale Sci & Technol, Gaithersburg, MD 20899 USA
[4] Univ Maryland, Inst Res Elect & Appl Phys, College Pk, MD 20742 USA
基金
美国国家科学基金会;
关键词
METAL-SURFACES; SYSTEMS; HEAT; NANOSCALE;
D O I
10.1103/PhysRevB.98.134306
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We present a protocol for the study of the dynamics and thermodynamics of quantum systems strongly coupled to a bath and subject to an external modulation. Our protocol quantifies the evolution of the system-bath composite by expanding the full density matrix as a series in the powers of the modulation rate, from which the functional form of work, heat, and entropy rates can be obtained. Under slow driving, thermodynamic laws are established. The entropy production rate is positive and is found to be related to the excess work dissipated by friction, at least up to second order in the driving speed. As an example of the present methodology, we reproduce the results for the quantum thermodynamics of the driven resonance level model. We also emphasize that our formalism is quite general and allows for electron-electron interactions, which can give rise to exotic Kondo resonances appearing in thermodynamic quantities.
引用
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页数:15
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