Synthesis and characterization of decavanadates:: X-ray crystal structures of (H3O)2[M(H2O)6]2[V10O28H6]•4H2O (M= Co, Ni) and Na[H3N(CH2)2NH3]2.5[V10O28]•5H2O

被引：0

作者：

Khan, MI ^{[1
]}

Tabussum, S

Zheng, C

机构：

[1] IIT, Dept Biol Chem & Phys Sci, Chicago, IL 60616 USA

[2] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2000年 / 30卷 / 09期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, IR spectra and crystal structures of three new compounds: (H3O)(2) - [Ni(II)(H2O)(6)](2)[V10O28H6]. 4H(2)O, (1), (H3O)(2)[Co(II)(H2O)(6)](2)[V10O28H6]. 4H(2)O, (2), and Na[H3N(CH2)(2)NH3](2.5)[V10O28]. 5H(2)O, (3), are described. The isomorphous structures of compounds (1) and (2) contain discrete {V10O28} anionic clusters, (M(H2O)(6)}(2+) (M = Ni, Co) ions, and lattice water molecules. The crystal structure of compound (3) exhibits a complex hydrogen bonded network involving oxo groups of {V10O28} cluster and hydrogen atoms of the doubly protonated ethylenediammoniun ion, [H3N(CH2)(2)NH3](2+).

引用

页码：1773 / 1790

页数：18

共 50 条

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