Effect of salts on the solubility of phenolic compounds:: experimental measurements and modelling

被引:49
作者
Noubigh, Adel
Mgaidi, Arbi
Abderrabba, Manef
Provost, Elise
Furst, Walter
机构
[1] ENSTA, Lab Chim & Proc, F-75739 Paris 15, France
[2] IPEST, Lab Physicochim Mat, La Marsa 2070, Tunisia
[3] Fac Sci Tunis, Lab Chim Minerale Ind, Tunis 1060, Tunisia
关键词
phenolic compounds; solubility; salt effect; activity coefficient; modelling;
D O I
10.1002/jsfa.2762
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Phenolic compounds can be found in industrial or agricultural waste, such as waste water from olive mills. Because of the environmental problem caused by this residue from olive oil production, the aim of this work was to model the effect of salts on the solubility of four phenolic compounds. For this purpose, the solubilities of gallic acid, protocatechuic acid, vanillic acid and vanillin have been measured in various chloride solutions at constant temperature. The Clegg-Simonson-Pitzer activity coefficient, together with the dissociation constant obtained from the literature, has been used to represent the equilibrium solid-liquid data. Good agreement (3.4%) between the experimental and calculated values for solubility was obtained. (c) 2007 Society of Chemical Industry.
引用
收藏
页码:783 / 788
页数:6
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