A new organic-inorganic hybrid framework containing octahedral hexarhenium cluster and its transformation by ligand exchange

被引：14
|
作者：
Kim, Sehye
Kim, Youngmee
Kal, Yunseon
Kim, Sung-Jin
机构：
[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
[2] Ewha Womans Univ, Div Nano Sci, Seoul 120750, South Korea
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 06期
关键词：
coordination polymers; flexible metal-organic frameworks; metal clusters; hybrid materials; crystal-to-crystal transformation;
D O I：
10.1016/j.ica.2006.09.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new organic-inorganic hybrid solid with 3-D framework, [Mn(DMF)(3)](2)[Re6Se8(CN)(6)] (1), has been synthesized and transformed to [H][Mn(salen)](3)[Re6Se8(CN)(6)] (2) by a ligand exchange. Hexarhenium chalcocyanide clusters are closest packed in cubic symmetry for 1 and rhombohedral symmetry for 2. The manganese complexes in the interstitial sites are three-coordinated to the rhenium cluster in I and two-coordinated in 2. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：1870 / 1874
页数：5
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