A potential harmonic method for the three-body Coulomb problem

被引:3
|
作者
Bian, WS [1 ]
Deng, CH [1 ]
机构
[1] Shandong Univ, Inst Theoret Chem, Jinan 250100, Peoples R China
关键词
three-body problem; Schroedinger equation; potential harmonics; hyperspherical coordinate; generalized Laguerre function;
D O I
10.1007/s002140050284
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A potential harmonic method that is suitable for the three-body coulomb systems is presented. This method is applied to solve the three-body Schroedinger equations for He and e(+)e(-)e(+) directly, and the calculations yield very good results for the energy. For example, we obtain a ground-state energy of -0.26181 hartrees for e(+)e(-)e(+), and -2.90300 hartrees for He with finite nuclear mass, in good agreement with the exact values of -0.26200 hartrees and -2.90330 hartrees. Compared with the full-set calculations, the errors in the total energy for ground and excited states of e(+)e(-)e(+) are very small, around -0.0001 hartrees. We conclude that the present method is one of the best PH methods for the three-body coulomb problem.
引用
收藏
页码:110 / 116
页数:7
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