Dual-catalytic decarbonylation of fatty acid methyl esters to form olefins

被引：13

作者：

Fieser, Megan E. ^{[1
]}

Schimler, Sydonie D. ^{[1
]}

Mitchell, Lauren A. ^{[1
]}

Wilborn, Emily G. ^{[1
]}

John, Alex ^{[1
]}

Hogan, Levi T. ^{[1
]}

Benson, Brooke ^{[1
]}

LaPointe, Anne M. ^{[2
]}

Tolman, William B. ^{[1
,3
]}

机构：

[1] Univ Minnesota, Dept Chem, Ctr Sustainable Polymers, 207 Pleasant St SE, Minneapolis, MN 55455 USA

[2] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

[3] Washington Univ, Dept Chem, One Brookings Dr,Campus Box 1134, St Louis, MO 63130 USA

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 55期

基金：

美国国家科学基金会;

关键词：

ALIPHATIC CARBOXYLIC-ACIDS; ACYL-OXYGEN BONDS; ORGANOBORON COMPOUNDS; HYDROCARBON FUELS; COUPLING REACTION; DECARBOXYLATION; DEOXYGENATION; DEHYDRATION; ALKENES; BIOMASS;

D O I：

10.1039/c8cc03823f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The homogeneous dehydrative decarbonylation of fatty acid methyl esters (FAMEs) to form olefins is reported. In order to facilitate cleavage of the unactivated acyl C-O bond of the alkyl ester, a one pot dual-catalytic directing group strategy was developed through optimization of the individual transesterification and decarbonylation reaction steps.

引用

页码：7669 / 7672

页数：4

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