The improved Kolbe-Schmitt reaction using supercritical carbon dioxide

被引：22
作者：
Iijima, Takayuki [1 ]
Yamaguchi, Tatsuaki [1 ]
机构：
[1] Chiba Inst Technol, Fac Engn, Dept Life & Environm Sci, Narashino, Chiba 2750016, Japan
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 30期
关键词：
supercritical carbon dioxide; sodium phenoxide; salicylic acid; p-hydroxybenzoic acid; Kolbe-Schmitt reaction;
D O I：
10.1016/j.tetlet.2007.05.132
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A comparative analysis of the reactions between sodium phenoxide and CO2 under the gaseous and supercritical conditions has demonstrated the preferential effect of supercritical conditions for promoting the reactivity Of CO2. A significant increase in product yield was obtained in supercritical CO2 compared to reactions undertaken in gaseous CO2. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5309 / 5311
页数：3
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共 13 条
  • [1] Catalysis research of relevance to carbon management: Progress, challenges, and opportunities
    Arakawa, H
    Aresta, M
    Armor, JN
    Barteau, MA
    Beckman, EJ
    Bell, AT
    Bercaw, JE
    Creutz, C
    Dinjus, E
    Dixon, DA
    Domen, K
    DuBois, DL
    Eckert, J
    Fujita, E
    Gibson, DH
    Goddard, WA
    Goodman, DW
    Keller, J
    Kubas, GJ
    Kung, HH
    Lyons, JE
    Manzer, LE
    Marks, TJ
    Morokuma, K
    Nicholas, KM
    Periana, R
    Que, L
    Rostrup-Nielson, J
    Sachtler, WMH
    Schmidt, LD
    Sen, A
    Somorjai, GA
    Stair, PC
    Stults, BR
    Tumas, W
    [J]. CHEMICAL REVIEWS, 2001, 101 (04) : 953 - 996
  • [2] Effect of cation capture by crown ether and polar solvent in the carboxylation with CO2 of alkali metal 2-naphtholates under ordinary conditions
    Baxter, J
    Yamaguchi, T
    [J]. JOURNAL OF CHEMICAL RESEARCH-S, 1997, (10): : 374 - 375
  • [3] Supercritical and near-critical CO2 in green chemical synthesis and processing
    Beckman, EJ
    [J]. JOURNAL OF SUPERCRITICAL FLUIDS, 2004, 28 (2-3) : 121 - 191
  • [4] Homogeneous organic reactions as mechanistic probes in supercritical fluids
    Brennecke, JF
    Chateauneuf, JE
    [J]. CHEMICAL REVIEWS, 1999, 99 (02) : 433 - 452
  • [5] Diels-Alder reactions between maleic anhydride and furan derivatives in supercritical CO2
    Cott, DJ
    Ziegler, KJ
    Owens, VP
    Glennon, JD
    Graham, AE
    Holmes, JD
    [J]. GREEN CHEMISTRY, 2005, 7 (02) : 105 - 110
  • [6] Continuous hydrogenation reactions in supercritical CO2 "without gases''
    Hyde, JR
    Walsh, B
    Singh, J
    Poliakoff, M
    [J]. GREEN CHEMISTRY, 2005, 7 (05) : 357 - 361
  • [7] Continuous catalytic reactions in supercritical fluids
    Hyde, JR
    Licence, P
    Carter, D
    Poliakoff, M
    [J]. APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) : 119 - 131
  • [8] Carboxylation of 2-naphthol with carbon dioxide in anisole
    Iijima, Takayuki
    Iwase, Toru
    Yamaguchi, Tatsuaki
    [J]. JOURNAL OF THE JAPAN PETROLEUM INSTITUTE, 2006, 49 (04) : 206 - 209
  • [9] THE KOLBE-SCHMITT REACTION
    LINDSEY, AS
    JESKEY, H
    [J]. CHEMICAL REVIEWS, 1957, 57 (04) : 583 - 620
  • [10] Supercritical fluids: Introduction
    Noyori, R
    [J]. CHEMICAL REVIEWS, 1999, 99 (02) : 353 - 354
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