Bifunctional [c2]daisy-chains and their incorporation into mechanically interlocked polymers

被引：85
|
作者：
Guidry, Erin N.
Li, Jean
Stoddart, J. Fraser
Grubbs, Robert H.
机构：
[1] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[3] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Div Chem & Chem Engn, Pasadena, CA 91125 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 29期
关键词：
D O I：
10.1021/ja0725100
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A strategy for the formation of mechanically interlocked polymers is presented. Ring-closing olefin metathesis has been shown to provide a very high yielding route to [c2]daisy-chains suitably functionalized to allow their one-step conversion to bisolefins which can be used as monomers in ADMET polymerizations to afford mechanically interlocked polymers. Metathesis, in two different guises is making a hitherto unreachable goal in synthesis a reality.
引用
收藏
页码：8944 / +
页数：3
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