Light Switches the Ligand! Photochromic Azobenzene-Phosphanes

被引：37

作者：

Dolores Segarra-Maset, Maria ^{[1
]}

van Leeuwen, Piet W. N. M. ^{[1
]}

Freixa, Zoraida ^{[1
]}

机构：

[1] ICIQ, Inst Chem Res Catalonia, Tarragona 43007, Spain

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2010年 / 14期

关键词：

P ligands; Molecular switches; Azo compounds; Ligand effects; Homogeneous catalysis; RHODIUM-CATALYZED HYDROSILYLATION; CONTAINING PHOSPHINE COMPLEXES; BOWL-SHAPED PHOSPHINE; MOLECULAR-STRUCTURE; STRUCTURAL-CHARACTERIZATION; RATE ENHANCEMENT; METAL-COMPLEXES; CRYSTAL; PALLADIUM(II); TRIARYLPHOSPHINES;

D O I：

10.1002/ejic.201000063

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three phosphanes containing azobenzene groups were synthesized, and the photochemical behaviour of their platinum complexes was studied by using the light-induced (E)/(Z) isomerization as a switch to change ligand properties.

引用

页码：2075 / 2078

页数：4

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