Short O-O distances in edge sharing PO4 tetrahedra and VO6 octahedra of the vanadyl-orthophosphate CaNi(VO)(PO4)(2)

被引：0

作者：

Meyer, S ^{[1
]}

MullerBuschbaum, H ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 08期

关键词：

calcium; nickel; vanadium phosphate; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of the new compound CaNi(VO)(PO4)(2) have been prepared by solid state reactions below the melting point of the oxide mixture in evacuated quartz tubes. X-ray investigations led to orthorhombic symmetry, space group D-2h(16)-Pnma, a = 14.113(1), b = 6.408(1), c = 7.364(1) Angstrom, Z = 4. The crystal structure shows (1)(infinity)[NiO4] and (1)(infinity) [VO6P2O3] polyhedra chains closely related to analogous chains in the isotypic compound CdV2O(PO4)(2). The short V-O distance of 1.66 Angstrom indicates a vanadyl group as the main difference to CdV2O(PO4)(2). The short O-O distance of 2,395 Angstrom of the edge-sharing PO4 tetrahedra and VO6 octahedra is discussed.

引用

页码：981 / 984

页数：4

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