Catalytic [2,3]-sigmatropic rearrangement of sulfur ylide derived from metal carbene

被引：155

作者：

Zhang, Yan ^{[1
]}

Wang, Jianbo ^{[1
,2
]}

机构：

[1] Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,BNLMS, Beijing 100871, Peoples R China

[2] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2010年 / 254卷 / 9-10期

关键词：

2,3]-Sigmatropic rearrangement; Sulfur ylide; Metal carbene; Diazo compounds; Asymmetic catalysis; ALLYLIC SULFIDES; SULFONIUM YLIDE; CARBONYL-COMPOUNDS; ORGANIC-SYNTHESIS; DIAZO-COMPOUNDS; EPOXIDATION; INSERTION; CASCADE; WATER;

D O I：

10.1016/j.ccr.2009.12.005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reviews the most recent development of [2,3]-sigmatropic rearrangement of sulfur ylide generated from the reaction of sulfide with metal carbene The metal carbene was formed from decomposition of diazo compounds catalyzed by transition metal complexes such as Cu(I) and Rh(II) (C) 2009 Elsevier B.V All rights reserved.

引用

页码：941 / 953

页数：13

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