Willemite photoluminescence in Zn-implanted silica glasses

被引:6
作者
Zatsepin, Anatoly [1 ]
Buntov, Evgeny [1 ]
Kortov, Vsevolod [1 ]
Gavrilov, Nikolai [2 ]
Fitting, Hans-Joachim [3 ]
机构
[1] Ural Fed Univ, Mira St 19, Ekaterinburg 620002, Russia
[2] Russian Acad Sci, Inst Electrophys, Ekaterinburg 620002, Russia
[3] Univ Rostock, Inst Phys, D-18051 Rostock, Germany
来源
PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 12, NO 12 | 2015年 / 12卷 / 12期
关键词
willemite; photoluminescence; ion implantation; silica glass; LUMINESCENCE PROPERTIES; SIO2;
D O I
10.1002/pssc.201510099
中图分类号
O59 [应用物理学];
学科分类号
摘要
The photoluminescence properties of alpha-Zn2SiO4 nanoparticles formed in the SiO2 by means of ion implantation and subsequent 900 degrees C, 1 hour annealing in air atmosphere. Both X-ray diffraction, optical and photoluminescence (PL) spectra confirm the formation of willemite phase Zn2SiO4 in SiO2 matrices. The characteristic 2.4 eV PL band observed resembles the properties of classi-cal Zn2SiO4: Mn phosphor, though no manganese were introduced into the samples. PL excitation spectra demonstrate the contribution of willemite and silica band states, thus suggesting interphase energy transfer mechanism. Thermal quenching and lifetimes of the luminescence observed provide the clues to figure out the nature of emission centres. (C) 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
引用
收藏
页码:1355 / 1358
页数:4
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