Thermal runaway reaction for highly exothermic material in safe storage temperature

被引：22

作者：

Lin, Chun-Ping ^{[1
,2
]}

Li, Jin-Shuh ^{[3
]}

Tseng, Jo -Ming ^{[4
]}

Mannan, S. Sam ^{[5
]}

机构：

[1] Asia Univ, Dept Hlth & Nutr Biotechnol, 500 Lioufeng Rd, Taichung 41354, Taiwan

[2] China Med Univ, Dept Occupat Safety & Hlth, 91 Hsueh Shih Rd, Taichung 40402, Taiwan

[3] Natl Def Univ, Dept Chem & Mat Engn, 75 Shiyuan Rd, Taoyuan 33551, Taiwan

[4] Cent Taiwan Univ Sci & Technol, Dept Safety Hlth & Environm Engn, 666 Buzih Rd, Taichung 40601, Taiwan

[5] Texas A&M Univ, Chem Engn, College Stn, TX 77843 USA

来源：

JOURNAL OF LOSS PREVENTION IN THE PROCESS INDUSTRIES | 2016年 / 40卷

关键词：

Highly exothermic material; Thermal reactive materials; Differential scanning calorimetry; Safety parameter; Loss prevention; NITROGEN-CONTENT; DSC; NITROCELLULOSE; THERMOLYSIS; DECOMPOSITION; DEGRADATION; EXPLOSIVES; STABILIZER; KINETICS; ENERGY;

D O I：

10.1016/j.jlp.2016.01.006

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Highly exothermic materials have caused many serious accidents involving storage and transportation, due to being thermally reactive. The safe storage and management of these materials is still a critical problem in many countries. Our aim was to study the thermal hazard of thermal reactive materials, such as a propellant, by employing differential scanning calorimetry (DSC) non-isothermal tests and isothermal tests, and then comparing the kinetic parameters by isothermal and non-isothermal of kinetics. The chosen approach was to obtain reliable thermal decomposition by a safe and effective method, which acquired the kinetic and safety parameters of storage conditions that could be applied as highly exothermic materials' reduction of loss prevention and energy potential for safer design during storage transport and processing operations. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：259 / 265

页数：7

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