cis-Dicarbonyl-cis-dichlorido-trans-bis(triphenylphosphine-κP)iridium(III)-tetrafluoridoborate, formed by reaction of (cycloocta-1,5-diene)-bis(triphenylphosphine)iridium tetrafluoridoborate with carbonyl fluoride in dichloromethane solution

被引：0
作者：
Harding, Duncan A. J. [1 ]
Hope, Eric G. [1 ]
Solan, Gregory A. [1 ]
Fawcett, John [1 ]
机构：
[1] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2007年 / 63卷
关键词：
D O I：
10.1107/S0108270107025358
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction between carbonyl fluoride and [Ir(COD)( PPh3)(2)]BF4 (COD is cycloocta-1,5-diene) in dichloromethane solution affords the novel title iridium salt, [IrCl2(C18H15P)(2)- (CO)(2)]BF4. The cation lies across a twofold rotation axis in the space group P2(1)2(1)2 and its structure confirms the presence in a cis relationship of two metal-bound chlorides, while the phosphine ligands occupy a trans pair of sites. The anion also lies across a twofold rotation axis, and the F atoms are disordered over two sets of sites.
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页码：M321 / M322
页数：2
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