Synthesis and crystal structure of [Sb(mpo)2Cl] (Hmpo=2-mercaptopyridine N-oxide)

被引：0
|
作者：
Niu, DZ [1 ]
Wang, JH
Lu, ZS
Chen, JT
机构：
[1] Xuzhou Normal Univ, Dept Chem, Xuzhou 221009, Jiangsu, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 23卷 / 11期
关键词：
antimony(III); 2-mercaptopyridine N-oxide; crystal structure Psi-coordinated polyhedron;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound C10H8ClN2O2S2Sb was synthesized by the reaction Of [C5H5NH][SbCl4] with Nampo (Hmpo = 2-thiopyridine noxide). X-ray single-crystal structure analysis showed that the crystal, is of triclinic, space group P $(1) over bar $ with M-r = 409.50, a = 9.4022(6), b = 10.2910(7), c = 14.4631(9) Angstrom, alpha = 104.3210(10), beta = 96.9780(10), gamma = 90.1790(10)degrees, Z = 4, D-c = 2.022 g/cm(3), mu = 2.553 mm(-1), F(000) = 792, R = 0.0368 and wR = 0.0854. In the molecule, each antimony atom is coordinated with two sulfur, two oxygen and one chlorine atoms.
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页码：1308 / 1311
页数：4
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