Continuous purification of H2SO4 and HI phases by packed column in IS process

被引：35

作者：

Guo, H. F. ^{[1
]}

Zhang, P. ^{[1
]}

Bai, Y. ^{[1
]}

Wang, L. J. ^{[1
]}

Chen, S. Z. ^{[1
]}

Xu, J. M. ^{[1
]}

机构：

[1] Tsinghua Univ, INET, Beijing 100084, Peoples R China

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2010年 / 35卷 / 07期

关键词：

IS process; H2SO4; phase; HI phase; Purification; Packed column; THERMOCHEMICAL HYDROGEN-PRODUCTION; IODINE; CYCLE; DECOMPOSITION; EFFICIENCY; WATER;

D O I：

10.1016/j.ijhydene.2009.05.009

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Iodine-sulfur (IS) thermo-chemical water-splitting process is a promising technology to produce hydrogen using solar or nuclear energy. To avoid the undesirable side reactions between HI and H2SO4 phases formed in Bunsen reaction of IS cycle, it is necessary to purify the two phases. The purification process could be achieved by reverse reaction of Bunsen reaction. In this paper, the purification process in continuous mode by reacting sulfuric acid and HI in a packed column was experimentally studied; the influences of operational parameters, including the reaction temperature, the flow rate of nitrogen gas, and the flow rate of the raw material solutions, on the purification efficiency, were investigated in detail. Based on the results, the suitable conditions for continuous purification process of two phases were proposed. (C) 2009 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.

引用

页码：2836 / 2839

页数：4

共 17 条

[1]

BAE KK, 2006, P WHEC 16 LYON FRANC

[2]

BAI Y, 2009, CHIN APPL CHEM, V22, P292

[3] Purification of Sulfuric and Hydriodic Acids Phases in the Iodine-sulfur Process [J].