Metal-organic frameworks: structure, properties, methods of synthesis and characterization

被引：328
|
作者：
Butova, V. V. [1 ]
Soldatov, M. A. [1 ]
Guda, A. A. [1 ]
Lomachenko, K. A. [1 ,2 ,3 ]
Lamberti, C. [1 ,2 ,3 ]
机构：
[1] Southern Fed Univ, Int Res Ctr Smart Mat, Ul Zorge 5, Rostov Na Donu 344090, Russia
[2] Univ Turin, Dept Chem, NIS Interdept Ctr, INSTM Reference Ctr, Via P Giuria 7, I-10125 Turin, Italy
[3] Univ Turin, Dept Chem, CrisDi Interdept Ctr, INSTM Reference Ctr, Via P Giuria 7, I-10125 Turin, Italy
来源：
RUSSIAN CHEMICAL REVIEWS | 2016年 / 85卷 / 03期
关键词：
POROUS COORDINATION POLYMERS; CARBON-DIOXIDE CAPTURE; CHROMIUM TEREPHTHALATE MIL-101; ROOM-TEMPERATURE SYNTHESIS; ENHANCED HYDROGEN STORAGE; HIGH PROTON CONDUCTIVITY; AB-INITIO CALCULATIONS; HYDROTHERMAL SYNTHESIS; MOLECULAR-SIEVE; MICROWAVE SYNTHESIS;
D O I：
10.1070/RCR4554
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This review deals with key methods of synthesis and characterization of metal-organic frameworks (MOFs). The modular structure affords a wide variety of MOFs with different active metal sites and organic linkers. These compounds represent a new stage of development of porous materials in which the pore size and the active site structure can be modified within wide limits. The set of experimental methods considered in this review is sufficient for studying the short-range and long-range order of the MOF crystal structure, determining the morphology of samples and elucidating the processes that occur at the active metal site in the course of chemical reactions. The interest in metal-organic frameworks results, first of all, from their numerous possible applications, ranging from gas separation and storage to chemical reactions within the pores.
引用
收藏
页码：280 / 307
页数：28
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