Synthesis, Crystal Structure, and Electronic Properties of High-Pressure PdF2-Type Oxides MO2 (M = Ru, Rh, Os, Ir, Pt)

被引：22

作者：

Shirako, Yuichi ^{[1
]}

Wang, Xia ^{[2
]}

Tsujimoto, Yoshihiro ^{[3
]}

Tanaka, Kie ^{[1
]}

Guo, Yanfeng ^{[2
]}

Matsushita, Yoshitaka ^{[4
]}

Nemoto, Yoshihiro ^{[5
]}

Katsuya, Yoshio ^{[4
]}

Shi, Youguo ^{[2
,6
]}

Mori, Daisuke ^{[1
]}

Kojitani, Hiroshi ^{[1
]}

Yamaura, Kazunari ^{[2
,7
]}

Inaguma, Yoshiyuki ^{[1
]}

Akaogi, Masaki ^{[1
]}

机构：

[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

[2] Natl Inst Mat Sci, Superconducting Properties Unit, Tsukuba, Ibaraki 3050044, Japan

[3] Natl Inst Mat Sci, Mat Proc Unit, Tsukuba, Ibaraki 3050044, Japan

[4] Natl Inst Mat Sci, NIMS Beamline Stn SPring 8, Mikazuki, Hyogo 6795148, Japan

[5] Natl Inst Mat Sci, Res Network & Facil Serv Div, Tsukuba, Ibaraki 3050047, Japan

[6] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

[7] Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 21期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

PYRITE-STRUCTURE; MAGNETIC-PROPERTIES; 3-DIMENSIONAL VISUALIZATION; ELECTRICAL-PROPERTIES; DICHALCOGENIDES; PEROXIDE; PHASE; TRANSITIONS; DISULFIDES; REFINEMENT;

D O I：

10.1021/ic501770g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polycrystalline MO2's (HP-PdF2-type MO2, M = Rh, Os, Pt) with high-pressure PdF2 compounds were successfully synthesized under high-pressure conditions for the first time, to the best of our knowledge. The crystal structures and electromagnetic properties were studied. Previously unreported electronic properties of the polycrystalline HP-PdF2-type RuO2 and IrO2 were also studied. The refined structures clearly indicated that all compounds crystallized into the HP-PdF2-type structure, M4+O22-, rather than the pyrite-type structure, Mn+(O-2)(n-) (n < 4). The MO2 compounds (M = Ru, Rh, Os, Ir) exhibited metallic conduction, while PtO2 was highly insulating, probably because of the fully occupied t2g band. Neither superconductivity nor a magnetic transition was detected down to a temperature of 2 K, unlike the case of 3d transition metal chalcogenide pyrites.

引用

页码：11616 / 11625

页数：10

共 42 条

[31] Synthesis, crystal structure and magnetic properties of Ba5Ru2O9(O2), Ba5Nb2O9(O2) and Ba5Ru2O10 related to the perovskite-type structure, and structural relationships with corresponding sulfides [J].

Grasset, F ;

Zakhour, M ;

Darriet, J .

JOURNAL OF ALLOYS AND COMPOUNDS, 1999, 287 (1-2) :25-31

[32] High-pressure synthesis, crystal structure, and structural relationship of the first ytterbium fluoride borate Yb5(BO3)2F9 [J].

Haberer, Almut ;

Huppertz, Hubert .

JOURNAL OF SOLID STATE CHEMISTRY, 2009, 182 (04) :888-895

[33] High-pressure syntheses and crystal structure analyses of a new low-density CaFe2O4-related and CaTi2O4-type MgAl2O4 phases [J].

Ishii, Takayuki ;

Criniti, Giacomo ;

Bykova, Elena ;

Dubrovinsky, Leonid ;

Katsura, Tomoo ;

Arii, Hidekazu ;

Kojitani, Hiroshi ;

Akaogi, Masaki .

AMERICAN MINERALOGIST, 2021, 106 (07) :1105-1112

[34] Synthesis, Crystal and Electronic Structures, and Physical Properties of the Novel Compounds LaR4Mo36O52 (R = Dy, Er, Yb, and Y) Containing Infinite Chains of Trans-Edge-Shared Mo6 Octahedra and Mo2 Pairs and Rectangular Mo4 Clusters with Triple Mo-Mo Bonds [J].

Barrier, N. ;

Fontaine, B. ;

Pierrefixe, S. ;

Gautier, R. ;

Gougeon, P. .

INORGANIC CHEMISTRY, 2009, 48 (08) :3848-3856

[35] A shallow origin of so-called ultrahigh-pressure chromitites, based on single-crystal X-ray structure analysis of the high-pressure Mg2Cr2O5 phase, with modified ludwigite-type structure [J].

Ishii, Takayuki ;

Tsujino, Noriyoshi ;

Arii, Hidekazu ;

Fujino, Kiyoshi ;

Miyajima, Nobuyoshi ;

Kojitani, Hiroshi ;

Kunimoto, Takehiro ;

Akaogi, Masaki .

AMERICAN MINERALOGIST, 2017, 102 (10) :2113-2118

[36] High-Pressure/High-Temperature Synthesis of the Lanthanoid Zinc Borates Ln 2Zn(B2O5)2 (Ln = Eu, Tb, Yb, Lu) with a Gadolinite-Analogue Crystal Structure and Luminescence Properties of Tb2Zn(B2O5)2:Eu3+ [J].

Teichtmeister, Tobias A. ;

Foerster, Tom ;

Bernhart, Alexander Hugo ;

Seibald, Markus ;

Suta, Markus ;

Huppertz, Hubert .

CHEMISTRY OF MATERIALS, 2024, 36 (23) :11462-11477

[37] Preparation and crystal structure of ternary rare-earth platinum metal aluminides R2T3Al9 (T= Rh, Ir, Pd) with Y2Co3Ga9-type structure and magnetic properties of the iridium compounds [J].

Niermann, J ;

Fehrmann, B ;

Wolff, MW ;

Jeitschko, W .

JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (07) :2600-2609

[38] First-principles calculations to investigate structural, elastic, electronic, optical and thermal properties of La-based ternary intermetallic superconductors LaM2Si2 (M1/4Co, Cu, Rh, Pd, Ag, Ir, Pt, Au) [J].

Rahman, Md. Atikur ;

Khatun, Rukaia ;

Ferdous, Rejuana ;

Roy, Dayal Chandra ;

Hasan, Md. Zahid ;

Irfan, Ahmad ;

Sarker, Md. Abdur Razzaque ;

Hossain, Md. Mukter ;

Hossain, Aslam ;

Mouna, Sarah Chaba ;

Sarker, Sushmita .

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T, 2023, 26 :3840-3862

[39] Synthesis under high pressure: crystal structure and properties of cubic Dy36O11F50[AsO3]12 • H2O [J].

Goerigk, Felix Christian ;

Locke, Ralf Jules Christian ;

Schleid, Thomas .

FRONTIERS IN CHEMISTRY, 2024, 12

[40] High-Pressure Synthesis, Crystal Structures, and Properties of A-Site Columnar-Ordered Quadruple Perovskites NaRMn2Ti4O12 with R = Sm, Eu, Gd, Dy, Ho, Y [J].

Liu, Ran ;

Scatena, Rebecca ;

Khalyavin, Dmitry D. ;

Johnson, Roger D. ;

Inaguma, Yoshiyuki ;

Tanaka, Masahiko ;

Matsushita, Yoshitaka ;

Yamaura, Kazunari ;

Belik, Alexei A. .

INORGANIC CHEMISTRY, 2020, 59 (13) :9065-9076

← 1 2 3 4 5 →