Synthesis, Crystal Structure, and Electronic Properties of High-Pressure PdF2-Type Oxides MO2 (M = Ru, Rh, Os, Ir, Pt)

被引：22

作者：

Shirako, Yuichi ^{[1
]}

Wang, Xia ^{[2
]}

Tsujimoto, Yoshihiro ^{[3
]}

Tanaka, Kie ^{[1
]}

Guo, Yanfeng ^{[2
]}

Matsushita, Yoshitaka ^{[4
]}

Nemoto, Yoshihiro ^{[5
]}

Katsuya, Yoshio ^{[4
]}

Shi, Youguo ^{[2
,6
]}

Mori, Daisuke ^{[1
]}

Kojitani, Hiroshi ^{[1
]}

Yamaura, Kazunari ^{[2
,7
]}

Inaguma, Yoshiyuki ^{[1
]}

Akaogi, Masaki ^{[1
]}

机构：

[1] Gakushuin Univ, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

[2] Natl Inst Mat Sci, Superconducting Properties Unit, Tsukuba, Ibaraki 3050044, Japan

[3] Natl Inst Mat Sci, Mat Proc Unit, Tsukuba, Ibaraki 3050044, Japan

[4] Natl Inst Mat Sci, NIMS Beamline Stn SPring 8, Mikazuki, Hyogo 6795148, Japan

[5] Natl Inst Mat Sci, Res Network & Facil Serv Div, Tsukuba, Ibaraki 3050047, Japan

[6] Chinese Acad Sci, Inst Phys, Beijing 100190, Peoples R China

[7] Hokkaido Univ, Grad Sch Chem Sci & Engn, Sapporo, Hokkaido 0600810, Japan

来源：

INORGANIC CHEMISTRY | 2014年 / 53卷 / 21期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

PYRITE-STRUCTURE; MAGNETIC-PROPERTIES; 3-DIMENSIONAL VISUALIZATION; ELECTRICAL-PROPERTIES; DICHALCOGENIDES; PEROXIDE; PHASE; TRANSITIONS; DISULFIDES; REFINEMENT;

D O I：

10.1021/ic501770g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The polycrystalline MO2's (HP-PdF2-type MO2, M = Rh, Os, Pt) with high-pressure PdF2 compounds were successfully synthesized under high-pressure conditions for the first time, to the best of our knowledge. The crystal structures and electromagnetic properties were studied. Previously unreported electronic properties of the polycrystalline HP-PdF2-type RuO2 and IrO2 were also studied. The refined structures clearly indicated that all compounds crystallized into the HP-PdF2-type structure, M4+O22-, rather than the pyrite-type structure, Mn+(O-2)(n-) (n < 4). The MO2 compounds (M = Ru, Rh, Os, Ir) exhibited metallic conduction, while PtO2 was highly insulating, probably because of the fully occupied t2g band. Neither superconductivity nor a magnetic transition was detected down to a temperature of 2 K, unlike the case of 3d transition metal chalcogenide pyrites.

引用

页码：11616 / 11625

页数：10

共 42 条

[21] Single-Crystal Structure of HP-Sc2TeO6 Prepared by High-Pressure/High-Temperature Synthesis [J].

Ziegler, Raimund ;

Tribus, Martina ;

Hejny, Clivia ;

Heymann, Gunter .

CRYSTALS, 2021, 11 (12)

[22] High-pressure magnetic, electronic, and structural properties of MFe2O4 (M = Mg, Zn, Fe) ferric spinels [J].

Greenberg, E. ;

Xu, W. M. ;

Nikolaevsky, M. ;

Bykova, E. ;

Garbarino, G. ;

Glazyrin, K. ;

Merkel, D. G. ;

Dubrovinsky, L. ;

Pasternak, M. P. ;

Rozenberg, G. Kh. .

PHYSICAL REVIEW B, 2017, 95 (19)

[23] High-pressure synthesis of borate-nitrates: crystal structure of M3B7O13(NO3) (M = Co2+, Ni2+, Cu2+, Zn2+, Cd2+) [J].

Pasqualini, Leonard C. ;

Huppertz, Hubert .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2022, 77 (10) :719-725

[24] High pressure synthesis, crystal structure, and magnetic properties of the double-perovskite Sr2FeOsO6 [J].

Feng, Hai Luke ;

Tsujimoto, Yoshihiro ;

Guo, Yanfeng ;

Sun, Ying ;

Sathish, Clastin I. ;

Yamaura, Kazunari .

HIGH PRESSURE RESEARCH, 2013, 33 (01) :221-228

[25] High-Pressure Synthesis and Ferrimagnetism of Ni3TeO6-Type Mn2ScMO6 (M = Nb, Ta) [J].

Feng, Hai L. ;

Deng, Zheng ;

Croft, Mark ;

Lapidus, Saul H. ;

Zu, Rui ;

Gopalan, Venkatraman ;

Grams, Christoph P. ;

Hemberger, Joachim ;

Liu, Sizhan ;

Tyson, Trevor A. ;

Frank, Corey E. ;

Jin, Changqing ;

Walker, David ;

Greenblatt, Martha .

INORGANIC CHEMISTRY, 2019, 58 (23) :15953-15961

[26] Core-Shell versus Other Structures in Binary Cu38-n Mn Nanoclusters (M = Ru, Rh, Pd, Ag, Os, Ir, Pt, and Au; n=1, 2, and 6): Theoretical Insight into Determining Factors [J].

Takagi, Nozomi ;

Ishimura, Kazuya ;

Matsui, Masafuyu ;

Fukuda, Ryoichi ;

Ehara, Masahiro ;

Sakaki, Shigeyoshi .

JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (19) :10514-10528

[27] High-pressure/high-temperature synthesis and characterization of the first palladium or platinum containing lithium transition-metal sulfides Li2M3S4 (M=Pd, Pt) [J].

Heymann, Gunter ;

Niehaus, Oliver ;

Krueger, Hannes ;

Selter, Philipp ;

Brunklaus, Gunther ;

Poettgen, Rainer .

JOURNAL OF SOLID STATE CHEMISTRY, 2016, 242 :87-95

[28] Rare earth-rich compounds RE9TMg4 (RE = Y, Dy-Tm, Lu; T = Ru, Rh, Os, Ir) with an ordered Co2Al5-type structure [J].

Stein, Sebastian ;

Matar, Samir F. ;

Heletta, Lukas ;

Poettgen, Rainer .

SOLID STATE SCIENCES, 2018, 82 :70-77

[29] Exploring Brannerite-Type Mg1-xMxV2O6 (M = Mn, Cu, Co, or Ni) Oxides: Crystal Structure and Optical Properties [J].

Hsu, Hua-Chien ;

Lakshminarasimhan, Narayanan ;

Li, Jun ;

Ramirez, Arthur P. ;

Subramanian, Mas A. .

CRYSTALS, 2025, 15 (01)

[30] Synthesis, crystal structure and characterization of new 12H hexagonal perovskite-related oxides Ba6M2Na2X2O17 (M = Ru, Nb, Ta, Sb; X = V, Cr, Mn, P, As) [J].

Quarez, E ;

Abraham, F ;

Mentré, O .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 176 (01) :137-150

← 1 2 3 4 5 →