Low-Cost Carbazole-Based Hole-Transport Material for Highly Efficient Perovskite Solar Cells

被引：45

作者：

Chen, Zhiliang ^{[1
]}

Li, Hui ^{[2
]}

Zheng, Xiaolu ^{[1
]}

Zhang, Qi ^{[1
]}

Li, Zhanfeng ^{[2
]}

Hao, Yuying ^{[2
]}

Fang, Guojia ^{[1
]}

机构：

[1] Wuhan Univ, Key Lab Artificial Micro & Nanostruct, Minist Educ China, Sch Phys & Technol, Wuhan 430072, Hubei, Peoples R China

[2] Taiyuan Univ Technol, Key Lab Adv Transducers & Intelligent Control Sys, Minist Educ & Shanxi Prov, Coll Phys & Optoelect, Taiyuan 030024, Shanxi, Peoples R China

来源：

CHEMSUSCHEM | 2017年 / 10卷 / 15期

基金：

中国国家自然科学基金;

关键词：

carbazoles; hole-transport material; nitrogen heterocycles; perovskite; solar cells; COPPER PHTHALOCYANINE; HIGH-PERFORMANCE; LAYERS;

D O I：

10.1002/cssc.201700678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A low-cost carbazole-based small-molecule material, 1,3,6,8-tetra(N,N-p-dimethoxyphenylamino)-9-ethylcarbazole, was designed and synthesized through a facile three-step synthetic route. The material was characterized and applied as a holetransport material (HTM) for low-temperature-processed planar perovskite solar cells (PSCs). Devices based on this new HTM exhibit a high power-conversion efficiency of 17.8% that is comparable to that of PSCs based on the costly 2,2',7,7'-tetrakis[N,N-di(4-methoxyphenyl) amino]-9,9'-spirobifluorene (Spiro-OMeTAD) (18.6%).

引用

页码：3111 / 3117

页数：7

共 41 条

[1] Facile synthesized organic hole transporting material for perovskite solar cell with efficiency of 19.8%
Bi, Dongqin
Xu, Bo
Gao, Peng
Sun, Licheng
Graetzel, Michael
Hagfeldt, Anders
[J]. NANO ENERGY, 2016, 23 : 138 - 144
[2] Electrochemical Considerations for Determining Absolute Frontier Orbital Energy Levels of Conjugated Polymers for Solar Cell Applications
Cardona, Claudia M.
Li, Wei
Kaifer, Angel E.
Stockdale, David
Bazan, Guillermo C.
[J]. ADVANCED MATERIALS, 2011, 23 (20) : 2367 - 2371
[3] In Situ Generation of Poly (Vinylene Carbonate) Based Solid Electrolyte with Interfacial Stability for LiCoO2 Lithium Batteries
Chai, Jingchao
Liu, Zhihong
Ma, Jun
Wang, Jia
Liu, Xiaochen
Liu, Haisheng
Zhang, Jianjun
Cui, Guanglei
Chen, Liquan
[J]. ADVANCED SCIENCE, 2017, 4 (02):
[4] Bulk heterojunction perovskite solar cells based on room temperature deposited hole-blocking layer: Suppressed hysteresis and flexible photovoltaic application
Chen, Zhiliang
Yang, Guang
Zheng, Xiaolu
Lei, Hongwei
Chen, Cong
Ma, Junjie
Wang, Hao
Fang, Guojia
[J]. JOURNAL OF POWER SOURCES, 2017, 351 : 123 - 129
[5] Carbazole-based enamine: Low-cost and efficient hole transporting material for perovskite solar cells
Daskeviciene, Maryte
Paek, Sanghyun
Wang, Zhiping
Malinauskas, Tadas
Jokubauskaite, Gabriele
Rakstys, Kasparas
Cho, Kyung Taek
Magomedov, Artiom
Jankauskas, Vygintas
Ahmad, Shahzada
Snaith, Henry J.
Getautis, Vytautas
Nazeeruddin, Mohammad Khaja
[J]. NANO ENERGY, 2017, 32 : 551 - 557
[6] 14.8% perovskite solar cells employing carbazole derivatives as hole transporting materials
Do Sung, Sang
Kang, Min Soo
Choi, In Taek
Kim, Hong Mo
Kim, Hyoungjin
Hong, MunPyo
Kim, Hwan Kyu
Lee, Wan In
[J]. CHEMICAL COMMUNICATIONS, 2014, 50 (91) : 14161 - 14163
[7] Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals
Dong, Qingfeng
Fang, Yanjun
Shao, Yuchuan
Mulligan, Padhraic
Qiu, Jie
Cao, Lei
Huang, Jinsong
[J]. SCIENCE, 2015, 347 (6225) : 967 - 970
[8] Gratia P., 2015, Angew. Chem, V127, P11571, DOI [10.1002/ange.201504666, DOI 10.1002/ANGE.201504666]
[9] A Methoxydiphenylamine-Substituted Carbazole Twin Derivative: An Efficient Hole-Transporting Material for Perovskite Solar Cells
Gratia, Paul
Magomedov, Artiom
Malinauskas, Tadas
Daskeviciene, Maryte
Abate, Antonio
Ahmad, Shahzada
Graetzel, Michael
Getautis, Vytautas
Nazeeruddin, Mohammad Khaja
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (39) : 11409 - 11413
[10] Heo JH, 2013, NAT PHOTONICS, V7, P487, DOI [10.1038/nphoton.2013.80, 10.1038/NPHOTON.2013.80]

← 1 2 3 4 5 →