Facile activation of Si-H bond by an electrophilic carbene

被引：0

作者：

Swamy, V. S. V. S. N.

Kundu, Gargi

Sen, Sakya S. ^{[1
]}

机构：

[1] CSIR, Natl Chem Lab, Inorgan Chem & Catalysis Div, Dr Homi Bhabha Rd, Pune 411008, Maharashtra, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2018年 / 95卷 / 07期

关键词：

Phenlysilane; chlorosilanes; carbene; small molecules activation; ALKYL AMINO CARBENES; B-H; HYDROBORATION; ISOCYANIDES; SILICON(II); REACTIVITY; CATALYSTS; REAGENTS; CENTERS; AMMONIA;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein, we have explored the chemistry of 1,3-bis(2,6-di-isopropylphenyl)-5,5-dimethy1-4,6-diketopyrimidinyl-2-ylidene (1) with various silanes under mild conditions. The oxidative addition of Si-H bond of phenylsilane with DAC 1 affords the compound 2, which is unambiguously characterized by muitinuclear NMR spectroscopy, elemental analysis, and X-ray single crystal diffraction studies. Interestingly, DAC 1 activates silicon hydride bond of chlorosilanes at room temperature and results in the corresponding silylation products.

引用

页码：789 / 793

页数：5

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