Luminescence phenomena of carbon dots derived from citric acid and urea - a molecular insight

被引:240
作者
Kasprzyk, Wiktor [1 ]
Swiergosz, Tomasz [2 ]
Bednarz, Szczepan [1 ]
Walas, Karolina [1 ]
Bashmakova, Natalia V. [3 ]
Bogdal, Dariusz [1 ]
机构
[1] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Biotechnol & Phys Chem, 24 Warszawska St, PL-32048 Krakow, Poland
[2] Cracow Univ Technol, Fac Chem Engn & Technol, Dept Analyt Chem, 24 Warszawska St, PL-32048 Krakow, Poland
[3] Taras Shevchenko Natl Univ Kyiv, Fac Phys, Dept Expt Phys, Kiev, Ukraine
关键词
GRAPHENE QUANTUM DOTS; CHEMICAL-STRUCTURE; NANODOTS; PHOTOLUMINESCENCE; NANOPARTICLES; FLUOROPHORES; YIELD; FLUORESCENCE; PYROLYSIS; EMISSION;
D O I
10.1039/c8nr03602k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this report, we present the results of our investigations into the elucidation of the chemical structure of moieties responsible for the blue and green luminescence of CDs derived from the micro-wave-assisted pyrolysis of citric acid in the presence of urea. The molecular fluorophore that forms during the synthesis of green fluorescing CDs is 4-hydroxy-1H-pyrrolo[3,4-c]pyridine-1,3,6 (2H,5H)-trione (HPPT).
引用
收藏
页码:13889 / 13894
页数:6
相关论文
共 51 条
[1]   PREPARATION AND PROPERTIES OF ISOCYANIC ACID [J].
BELSON, DJ ;
STRACHAN, AN .
CHEMICAL SOCIETY REVIEWS, 1982, 11 (01) :41-56
[2]   The origin of emissive states of carbon nanoparticles derived from ensemble-averaged and single-molecular studies [J].
Demchenko, Alexander P. ;
Dekaliuk, Mariia O. .
NANOSCALE, 2016, 8 (29) :14057-14069
[3]  
Distaso M., 2017, RSC ADV, V7, P24771
[4]   Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid [J].
Dong, Yongqiang ;
Shao, Jingwei ;
Chen, Congqiang ;
Li, Hao ;
Wang, Ruixue ;
Chi, Yuwu ;
Lin, Xiaomei ;
Chen, Guonan .
CARBON, 2012, 50 (12) :4738-4743
[5]   One-step and high yield simultaneous preparation of single- and multi-layer graphene quantum dots from CX-72 carbon black [J].
Dong, Yongqiang ;
Chen, Congqiang ;
Zheng, Xinting ;
Gao, Lili ;
Cui, Zhiming ;
Yang, Hongbin ;
Guo, Chunxian ;
Chi, Yuwu ;
Li, Chang Ming .
JOURNAL OF MATERIALS CHEMISTRY, 2012, 22 (18) :8764-8766
[6]   2-Pyridone-based fluorophores: Synthesis and fluorescent properties of pyrrolo[3,4-c]pyridine derivatives [J].
Ershov, Oleg V. ;
Fedoseev, Sergey V. ;
Ievlev, Mikhail Yu. ;
Belikov, Mikhail Yu. .
DYES AND PIGMENTS, 2016, 134 :459-464
[7]   Artifacts and Errors Associated with the Ubiquitous Presence of Fluorescent Impurities in Carbon Nanodots [J].
Essner, Jeremy B. ;
Kist, Jennifer A. ;
Polo-Parada, Luis ;
Baker, Gary A. .
CHEMISTRY OF MATERIALS, 2018, 30 (06) :1878-1887
[8]   Carbon Dots: A Unique Fluorescent Cocktail of Polycyclic Aromatic Hydrocarbons [J].
Fu, Ming ;
Ehrat, Florian ;
Wang, Yu ;
Milowska, Karolina Z. ;
Reckmeier, Claas ;
Rogach, Andrey L. ;
Stolarczyk, Jacek K. ;
Urban, Alexander S. ;
Feldmann, Jochen .
NANO LETTERS, 2015, 15 (09) :6030-6035
[9]   Rational design of high quality citric acid-derived carbon dots by selecting efficient chemical structure motifs [J].
Gao, Fang ;
Ma, Shiyao ;
Li, Jun ;
Dai, Kang ;
Xiao, Xincai ;
Zhao, Dan ;
Gong, Weifan .
CARBON, 2017, 112 :131-141
[10]  
Ginell R., 1956, US Patent, Patent No. 2752354