Synthesis and characterisation of Au(I)-(ITent) complexes

被引：17

作者：

Patrick, Scott R. ^{[1
]}

Collado, Alba ^{[1
]}

Meiries, Sebastien ^{[1
,2
]}

Slawin, Alexandra M. Z. ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Adionics, F-91380 Chilly Mazarin, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2015年 / 775卷

基金：

英国工程与自然科学研究理事会;

关键词：

Gold; N-Heterocyclic carbene; Synthesis; Sterics; N-HETEROCYCLIC CARBENE; PD-PEPPSI-IPENT; CROSS-COUPLING REACTIONS; SILVER-FREE PROTOCOLS; LOW-TEMPERATURE; RESTRICTED FLEXIBILITY; NHC COMPLEXES; LIGANDS; CATALYSIS; AMINATION;

D O I：

10.1016/j.jorganchem.2014.04.022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of novel [AuCl(ITent)] and [Au(OH)(ITent)] complexes is reported. They have been fully characterised and their steric parameters were assessed by calculating percent buried volumes and producing steric maps from their crystal structures in the solid state. (C) 2014 Published by Elsevier B.V.

引用

页码：152 / 154

页数：3

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