Strategy for Ultrafine Ni Fibers and Investigation of the Electromagnetic Characteristics

被引:102
作者
Gong, Chunhong [1 ,2 ]
Zhang, Jingwei [1 ]
Zhang, Xuefeng [3 ]
Yu, Laigui [1 ]
Zhang, Pingyu [1 ]
Wu, Zhishen [1 ]
Zhang, Zhijun [1 ]
机构
[1] Henan Univ, Minist Educ, Key Lab Special Funct Mat, Kaifeng 475004, Peoples R China
[2] Henan Univ, Coll Chem & Chem Engn, Kaifeng 475004, Peoples R China
[3] Dalian Univ Technol, Sch Mat Sci & Engn, Dalian 116024, Peoples R China
基金
美国国家科学基金会;
关键词
MAGNETIC-PROPERTIES; FIELD; NANOSTRUCTURES; NANOTUBULES; FABRICATION; NANOWIRES; CHAINS; ARRAY;
D O I
10.1021/jp100697x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A simple and practical approach for synthesizing ultrafine Ni fibers under normal pressure via the reduction of Ni2+ ions by hydrazine hydrate in the absence of any templates or external magnetic field is reported. The mechanisms and a simplified model of formation for the Ni fibers are proposed, and the correlated magnetic properties and electromagnetic characteristics of the Ni products are studied systematically. The results of a series of comparative studies indicate that the feeding sequence of the reactants and the concentration of NaOH solution are critical to controlling the shape of the target products from fiber to sphere. The Ni fibers have an enhanced magnetic coercivity compared with that of the Ni spheres. The composites filled with Ni fibers have an electromagnetic wave absorbance within the frequency range 2.0-18.0 GHz stronger than that for the Ni sphere-filled composites. Specifically, by properly adjusting the matching thicknesses, a minimum reflection loss (RL) of -39.5 dB at 4.8 GHz and an absorbance band of less than -20 dB within 3-16 GHz are obtained for the Ni fiber-filled composites, showing that the Ni fibers may have promising application for electromagnetic wave absorbance.
引用
收藏
页码:10101 / 10107
页数:7
相关论文
共 34 条
[1]   Facile Preparation and Electromagnetic Properties of Core-Shell Composite Spheres Composed of Aloe-like Nickel Flowers Assembled on Hollow Glass Spheres [J].
An, Zhenguo ;
Pan, Shunlong ;
Zhang, Jingjie .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (07) :2715-2721
[2]   Template free, large scale synthesis of cobalt nanowires using magnetic fields for alignment [J].
Athanassiou, E. K. ;
Grossmann, P. ;
Grass, R. N. ;
Stark, W. J. .
NANOTECHNOLOGY, 2007, 18 (16)
[3]  
Bao JC, 2001, ADV MATER, V13, P1631, DOI 10.1002/1521-4095(200111)13:21<1631::AID-ADMA1631>3.0.CO
[4]  
2-R
[5]   An array of iron nanowires encapsulated in polyaniline nanotubules and its magnetic behavior [J].
Cao, HQ ;
Xu, Z ;
Sheng, D ;
Hong, JM ;
Sang, H ;
Du, YW .
JOURNAL OF MATERIALS CHEMISTRY, 2001, 11 (03) :958-960
[6]   Microwave absorption properties and mechanism of cagelike ZnO/SiO2 nanocomposites [J].
Cao, Mao-Sheng ;
Shi, Xiao-Ling ;
Fang, Xiao-Yong ;
Jin, Hai-Bo ;
Hou, Zhi-Ling ;
Zhou, Wei ;
Chen, Yu-Jin .
APPLIED PHYSICS LETTERS, 2007, 91 (20)
[7]   Synthesis and self-assembly of fcc phase FePt nanorods [J].
Chen, Min ;
Pica, Timothy ;
Jiang, Ying-Bing ;
Li, Peng ;
Yano, Kazuaki ;
Liu, J. Ping ;
Datye, Abhaya K. ;
Fan, Hongyou .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (20) :6348-+
[8]   Magnetic-field-induced assemblies of cobalt nanoparticles [J].
Cheng, GJ ;
Romero, D ;
Fraser, GT ;
Walker, ARH .
LANGMUIR, 2005, 21 (26) :12055-12059
[9]   Preparation and microwave characterization of submicrometer-sized hollow nickel spheres [J].
Deng, YD ;
Liu, X ;
Shen, B ;
Liu, L ;
Hu, WB .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2006, 303 (01) :181-184
[10]   Fabrication of novel anisotropic magnetic microparticles [J].
Dyab, Amro K. F. ;
Ozmen, Mustafa ;
Ersoz, Mustafa ;
Paunov, Vesselin N. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (21) :3475-3481