On the construction of particle distributions with specified single and pair densities

被引:31
作者
Costin, O [1 ]
Lebowitz, JL [1 ]
机构
[1] Rutgers State Univ, Dept Math, New Brunswick, NJ 08854 USA
关键词
D O I
10.1021/jp047793m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We discuss necessary conditions for the existence of a probability distribution on particle configurations in d-dimensions, i.e., a point process, compatible with a specified density rho and radial distribution function g(r). In d = 1 we give necessary and sufficient criteria on rhog(r) for the existence of such a point process of renewal (Markov) type. We prove that these conditions are satisfied for the case g(r) = 0, r < D and g(r) = 1, r > D, if and only if rhoD less than or equal to e(-1): the maximum density obtainable from diluting a Poisson process. We then describe briefly necessary and sufficient conditions, valid in every dimension, for rhog(r) to specify a determinantal point process for which all n-particle densities, rho(n)(r(1),...,r(n)), are given explicitly as determinants. We give several examples.
引用
收藏
页码:19614 / 19618
页数:5
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