Cobalt(II) and iron(II) bis(2,2′: 6′,2"-terpyridine) complexes functionalized with alkynes and cobalt carbonyl clusters

被引：10

作者：

Constable, EC

Hart, CP

Housecroft, CE

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

[2] Univ Birmingham, Sch Chem Sci, Birmingham B15 2TT, W Midlands, England

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 6-7期

关键词：

2,2 ': 6 ',2 ''-terpyridine; cobalt(II); iron(II); carbonyl cluster; alkyne;

D O I：

10.1002/aoc.435

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The preparation and characterization of new cobalt(II) and iron(II) complexes containing alkyne or cobalt cluster functionalized 2,2': 6',2"-terpyridine ligands are described. The cobalt(II) complexes exhibit paramagnetically shifted, but well-resolved, H-1 NMR spectra that are characteristic of low-spin cobalt(II) solution species. Copyright (C) 2003 John Wiley Sons, Ltd.

引用

页码：383 / 387

页数：5

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