Study of polysiloxanes containing epoxy groups I. Synthesis and characterization of polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups

被引：34

作者：

Feng, SY ^{[1
]}

Cui, MZ ^{[1
]}

机构：

[1] Shandong Univ, Inst New Mat, Jinan 250100, Shandong, Peoples R China

来源：

REACTIVE & FUNCTIONAL POLYMERS | 2000年 / 45卷 / 02期

关键词：

polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups; base-catalyzed equilibration of cyclosiloxanes; hydrosilylation; allyl glycidyl ether;

D O I：

10.1016/S1381-5148(00)00013-4

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups were synthesized by two methods, copolymerization of cyclosiloxanes by base-catalyzed equilibration and hydrosilylation of allyl glycidyl ether with hydrogen-containing silicone oils. The effects of various factors on the reactions were investigated. The structures and epoxy content of the polysiloxanes were determined by IR and H-1-NMR spectra and potentiometric titration, respectively. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：79 / 83

页数：5