Study of polysiloxanes containing epoxy groups I. Synthesis and characterization of polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups

被引:34
作者
Feng, SY [1 ]
Cui, MZ [1 ]
机构
[1] Shandong Univ, Inst New Mat, Jinan 250100, Shandong, Peoples R China
关键词
polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups; base-catalyzed equilibration of cyclosiloxanes; hydrosilylation; allyl glycidyl ether;
D O I
10.1016/S1381-5148(00)00013-4
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Polysiloxanes containing 3-(2,3-epoxypropoxy)propyl groups were synthesized by two methods, copolymerization of cyclosiloxanes by base-catalyzed equilibration and hydrosilylation of allyl glycidyl ether with hydrogen-containing silicone oils. The effects of various factors on the reactions were investigated. The structures and epoxy content of the polysiloxanes were determined by IR and H-1-NMR spectra and potentiometric titration, respectively. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:79 / 83
页数:5
相关论文
共 24 条
[1]  
AOKI S, 1992, Patent No. 476925
[2]   THE SYNTHESIS, CHARACTERIZATION, AND PHOTOINITIATED CATIONIC POLYMERIZATION OF SILICON-CONTAINING EPOXY-RESINS [J].
CRIVELLO, JV ;
LEE, JL .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (03) :479-503
[3]  
CUI MZ, UNPUB CHIN J MAT RES
[4]  
DU ZD, 1987, CHINA SYNTH RUBBER I, V9, P309
[5]  
ECHBERG RP, 1992, RAD TECH REP, V6, P13
[6]  
FUJIEDA S, 1991, Patent No. 03281507
[7]  
HAMAMO I, 1991, Patent No. 03210321
[8]  
*I CHENG CHEM IND, 1986, SIL MON POL, P241
[9]  
IWAMOTO N, 1992, Patent No. 0407314
[10]  
LI Z, 1979, IND ANAL ORGANOSILIC, P90