Optical analysis of RE3+ (RE = Nd or Er):B2O3-P2O5-CaF2-ZnO-(Li2O/Na2O/K2O) glasses

被引:2
作者
Moulika, Guduru [1 ]
Sailaja, Sannapureddy [2 ]
Santhosh Vijitha, Jillela [1 ]
Bayapu Reddy, Putluru [1 ]
Shanthi Latha, Kondala [1 ]
Venkata Chalapathi, Gasthi [3 ]
Sudhakar Reddy, Busireddy [1 ]
机构
[1] Govt Coll Men A, Dept Phys, Kadapa 516004, Andhra Pradesh, India
[2] G Pulla Reddy Engn Coll Autonomous, Dept Humanities & Basic Sci, Kurnool, Andhra Pradesh, India
[3] Govt Degree Coll A, Dept Phys, Anantapur, Andhra Pradesh, India
关键词
alkali oxides; boro fluoro phosphate glasses; Nd3+ and Er3+ ions; LUMINESCENCE PROPERTIES; PHOSPHATE-GLASSES; EMISSION;
D O I
10.1002/bio.4259
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Calcium boro fluoro zinc phosphate glasses modified using alkali oxide and doped with Nd3+ and Er3+ ions with the chemical composition of 69.5 (B2O3) + 10 (P2O5) + 10 (CaF2) + 5 (ZnO) + 5 (Na2O/Li2O/K2O) + 0.5 (Er2O3/Nd2O3) were prepared using a conventional melt quenching technique. The results of X-ray diffraction patterns indicated the amorphous nature of all the prepared glasses. The visible-near-infrared red (NIR) absorption spectra of these glasses were analyzed systematically. The NIR emission spectra of Er3+ and Nd3+:calcium boro fluoro zinc phosphate glasses showed prominent emission bands at 1536 nm (I-4(13/2)-> I-4(15/2)) and 1069 nm (F-4(3/2)-> I-4(11/2)) respectively with lambda(exci) = 514.5 nm (Ar+ laser) as the excitation source.
引用
收藏
页码:1073 / 1077
页数:5
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