[2] Univ Ljubljana, Dept Phys, Ljubljana 1000, Slovenia
[3] Jozef Stefan Inst, Dept Theoret Phys, SI-1000 Ljubljana, Slovenia
来源:
JOURNAL OF CHEMICAL PHYSICS
|
2004年
/
121卷
/
15期
关键词:
D O I:
10.1063/1.1796234
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
We formulate and evaluate the van der Waals part of the free energy due to a dielectric profile that varies continuously throughout the space between two interacting bodies. Not considering the work needed to create the inhomogeneous dielectric profile, focusing only on that part of the free energy affected by the inhomogeneity, we compare the ensuing interaction free energy with that of the original Lifshitz formulation with its step function changes at material boundaries and uniform dielectric medium. Rather than the monotonically varying attraction between like bodies given by the original formulation, the inhomogeneous continuous dielectric function leads to attractions as well as repulsions. The Lifshitz result emerges naturally in the limit of separations much larger than the thickness of the interfaces. (C) 2004 American Institute of Physics.
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
de Oliveira, Raphaela
Yoshida, Ana B. Barbosa
论文数: 0引用数: 0
h-index: 0
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Nanotechnol Natl Lab LNNano, BR-13083100 Campinas, SP, Brazil
Univ Estadual Campinas, Gleb Wataghin Inst Phys, BR-13083970 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Yoshida, Ana B. Barbosa
Rabahi, Cesar R.
论文数: 0引用数: 0
h-index: 0
机构:
Univ Fed Sao Carlos, Dept Phys, BR-13565905 Sao Carlos, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Rabahi, Cesar R.
Freitas, Raul
论文数: 0引用数: 0
h-index: 0
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Freitas, Raul
Teixeira, Veronica C.
论文数: 0引用数: 0
h-index: 0
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Teixeira, Veronica C.
de Matos, Christiano J. S.
论文数: 0引用数: 0
h-index: 0
机构:
Mackenzie Presbyterian Inst, MackGraphe, BR-01302907 Sao Paulo, SP, Brazil
Univ Prebiteriana Mackenzie, Mackenzie Engn Sch, BR-01302907 Sao Paulo, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
de Matos, Christiano J. S.
Gobato, Yara Galvao
论文数: 0引用数: 0
h-index: 0
机构:
Univ Fed Sao Carlos, Dept Phys, BR-13565905 Sao Carlos, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Gobato, Yara Galvao
Barcelos, Ingrid D.
论文数: 0引用数: 0
h-index: 0
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
Barcelos, Ingrid D.
Cadore, Alisson R.
论文数: 0引用数: 0
h-index: 0
机构:
Brazilian Ctr Res Energy & Mat CNPEM, Brazilian Nanotechnol Natl Lab LNNano, BR-13083100 Campinas, SP, BrazilBrazilian Ctr Res Energy & Mat CNPEM, Brazilian Synchrotron Light Lab LNLS, BR-13083970 Campinas, SP, Brazil
机构:
Univ Colorado Boulder, Dept Phys, Boulder, CO 80309 USA
Univ Colorado Boulder, Ctr Theory Quantum Matter, Boulder, CO 80309 USA
Stanford Univ, Dept Phys, Stanford, CA 94305 USAUniv Colorado Boulder, Dept Phys, Boulder, CO 80309 USA