Van der Waals interactions in a dielectric with continuously varying dielectric function

被引:21
|
作者
Podgornik, R
Parsegian, VA
机构
[1] NICHD, Lab Phys & Struct Biol, NIH, Bethesda, MD 20892 USA
[2] Univ Ljubljana, Dept Phys, Ljubljana 1000, Slovenia
[3] Jozef Stefan Inst, Dept Theoret Phys, SI-1000 Ljubljana, Slovenia
来源
JOURNAL OF CHEMICAL PHYSICS | 2004年 / 121卷 / 15期
关键词
D O I
10.1063/1.1796234
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We formulate and evaluate the van der Waals part of the free energy due to a dielectric profile that varies continuously throughout the space between two interacting bodies. Not considering the work needed to create the inhomogeneous dielectric profile, focusing only on that part of the free energy affected by the inhomogeneity, we compare the ensuing interaction free energy with that of the original Lifshitz formulation with its step function changes at material boundaries and uniform dielectric medium. Rather than the monotonically varying attraction between like bodies given by the original formulation, the inhomogeneous continuous dielectric function leads to attractions as well as repulsions. The Lifshitz result emerges naturally in the limit of separations much larger than the thickness of the interfaces. (C) 2004 American Institute of Physics.
引用
收藏
页码:7467 / 7473
页数:7
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