Synthesis and transesterification of β-methoxycarbonyl-β-methylethyltin trichloride complexes with benzylmethylsulfoxide

被引：5

作者：

Tian, LJ ^{[1
]}

Zhou, ZY

Yu, QS

Liu, XJ

机构：

[1] Qufu Normal Univ, Dept Chem, Shandong 273165, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 2003年 / 33卷 / 02期

关键词：

alkyltin(IV) trichloride; transeterification; benzylmethylsulfoxide; crystal structure; orgaotin(IV) complex;

D O I：

10.1081/SIM-120017784

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis, crystal structure and transesterification reaction of the beta-methoxycarbonyl-beta-methylethyltin trichloride complex with benzyl-methylsulfoxide is reported and a possible mechanism for the transesterification is suggested. A series of complexes of beta-alkoxycarbonyl-beta-methylethyltin trichloride with benzylmethyl sulfoxide have been synthesized and characterized by elemental analyses, IR and H-1 NMR spectra.

引用

页码：259 / 269

页数：11

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