Coupling of breath figure method with interfacial polymerization: Bottom-surface funttionalized honeycomb-patterned porous films

被引：30
作者：
Male, Umashankar [1 ,2 ]
Shin, Bo Kyoung [1 ,2 ]
Huh, Do Sung [1 ,2 ]
机构：
[1] Inje Univ, Dept Chem, Obang 607, Gimhae City, South Korea
[2] Inje Univ, Dept Nanosci & Engn, Ctr Nanomfg, Obang 607, Gimhae City, South Korea
来源：
POLYMER | 2017年 / 119卷
基金：
新加坡国家研究基金会;
关键词：
Breath figure method; Patterned porous film; Polyaniline; Contact angle; Flexible film; Interfacial polymerization; POLYANILINE COMPOSITE FILMS; FABRICATION; CONDUCTIVITY; TEMPLATE; POLYMERS; DESIGN;
D O I：
10.1016/j.polymer.2017.05.038
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new and facile method was designed for the fabrication of asymmetrically polyaniline (PANI) functionalized polystyrene (PS) honeycomb-patterned porous films in a single step. The method involves the coupling of breath figure process with an interfacial polymerization, wherein the PS solution containing benzoyl peroxide in an organic solvent was cast under humid conditions over an aqueous solvent containing aniline and methane sulfonic acid. PANI was coated on the bottom surface at the organic/aqueous interface by an interfacial polymerization method, whereas a porous patterned PS was fabricated on the top surface by the breath figure method. The films revealed a translucent insulating PS top surface and a conducting green PANI bottom surface. The obtained films represented asymmetrical composition, color, morphology, conductivity, and contact angle on either surface. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码：206 / 211
页数：6
相关论文
共 32 条
[1]   Breath Figure Arrays: Unconventional Fabrications, Functionalizations, and Applications [J].
Bai, Hua ;
Du, Can ;
Zhang, Aijuan ;
Li, Lei .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (47) :12240-12255
[2]   Progress in preparation, processing and applications of polyaniline [J].
Bhadra, Sambhu ;
Khastgir, Dipak ;
Singha, Nikhil K. ;
Lee, Joong Hee .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (08) :783-810
[3]   Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications [J].
Ciric-Marjanovic, Gordana .
SYNTHETIC METALS, 2013, 177 :1-47
[4]   Recent advances in honeycomb-structured porous polymer films prepared via breath figures [J].
Escale, Pierre ;
Rubatat, Laurent ;
Billon, Laurent ;
Save, Maud .
EUROPEAN POLYMER JOURNAL, 2012, 48 (06) :1001-1025
[5]   Ordered porous structure hybrid films generated by breath figures for directional water penetration [J].
Guo, Tianqi ;
Han, Keyu ;
Heng, Liping ;
Cao, Moyuan ;
Jiang, Lei .
RSC ADVANCES, 2015, 5 (107) :88471-88476
[6]   Advances in Fabrication Materials of Honeycomb Structure Films by the Breath-Figure Method [J].
Heng, Liping ;
Wang, Bin ;
Li, Muchen ;
Zhang, Yuqi ;
Jiang, Lei .
MATERIALS, 2013, 6 (02) :460-482
[7]  
Karthaus O., 2012, SPIE NEWSROOM, P2, DOI 10.1117/2.1201207.004328
[8]   Preparation of Honeycomb-patterned Polyaniline-MWCNT/Polystyrene Composite Film and Studies on DC Conductivity [J].
Kim, Won Jung ;
Huh, Do Sung .
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (07) :2345-2351
[9]   Synthesis and properties of silica/polystyrene/polyaniline conductive composite particles [J].
Lee, CF ;
Tsai, HH ;
Wang, LY ;
Chen, CF ;
Chiu, WY .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (02) :342-354
[10]   A Bottom-Up Approach To Fabricate Patterned Surfaces with Asymmetrical TiO2 Microparticles Trapped in the Holes of Honeycomblike Polymer Film [J].
Li, Xiaofeng ;
Zhang, Liang ;
Wang, Yongxin ;
Yang, Xiaoli ;
Zhao, Ning ;
Zhang, Xiaoli ;
Xu, Jian .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (11) :3736-3739
1234