Exploring MXenes and their MAX phase precursors by electron microscopy

被引:62
作者
Alnoor, H. [1 ]
Elsukova, A. [1 ]
Palisaitis, J. [1 ]
Persson, I [1 ]
Tseng, E. N. [1 ]
Lu, J. [1 ]
Hultman, L. [1 ]
Persson, P. O. A. [1 ]
机构
[1] Linkoping Univ, Dept Phys Chem & Biol IFM, Thin Film Phys Div, SE-58183 Linkoping, Sweden
基金
瑞典研究理事会;
关键词
Electron microscopy; MAX phases; MXenes; 2D materials;
D O I
10.1016/j.mtadv.2020.100123
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This review celebrates the width and depth of electron microscopy methods and how these have enabled massive research efforts on MXenes. MXenes constitute a powerful recent addition to 2-dimensional materials, derived from their parent family of nanolaminated materials known as MAX phases. Owing to their rich chemistry, MXenes exhibit properties that have revolutionized ranges of applications, including energy storage, electromagnetic interference shielding, water filtering, sensors, and catalysis. Few other methods have been more essential in MXene research and development of corresponding applications, compared with electron microscopy, which enables structural and chemical identification at the atomic scale. In the following, the electron microscopy methods that have been applied to MXene and MAX phase precursor research are presented together with research examples and are discussed with respect to advantages and challenges. (C) 2020 The Author(s). Published by Elsevier Ltd.
引用
收藏
页数:16
相关论文
共 99 条
[71]   On the organization and thermal behavior of functional groups on Ti3C2 MXene surfaces in vacuum [J].
Persson, Ingemar ;
Naslund, Lars-Ake ;
Halim, Joseph ;
Barsoum, Michel W. ;
Darakchieva, Vanya ;
Palisaitis, Justinas ;
Rosen, Johanna ;
Persson, Per O. A. .
2D MATERIALS, 2018, 5 (01)
[72]   Current state of the art on tailoring the MXene composition, structure, and surface chemistry [J].
Persson, Per. O. A. ;
Rosen, Johanna .
CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2019, 23 (06)
[73]   A flexible semitransparent photovoltaic supercapacitor based on water-processed MXene electrodes [J].
Qin, Leiqiang ;
Jiang, Jianxia ;
Tao, Quanzheng ;
Wang, Chuanfei ;
Persson, Ingemar ;
Fahlman, Mats ;
Persson, Per O. A. ;
Hou, Lintao ;
Rosen, Johanna ;
Zhang, Fengling .
JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (11) :5467-5475
[74]   Effect of Postetch Annealing Gas Composition on the Structural and Electrochemical Properties of Ti2CTx MXene Electrodes for Supercapacitor Applications [J].
Rakhi, R. B. ;
Ahmed, Bilal ;
Hedhili, M. N. ;
Anjum, Dalaver H. ;
Alshareef, H. N. .
CHEMISTRY OF MATERIALS, 2015, 27 (15) :5314-5323
[75]   Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution [J].
Ramalingam, Vinoth ;
Varadhan, Purushothaman ;
Fu, Hui-Chun ;
Kim, Hyunho ;
Zhang, Daliang ;
Chen, Shuangming ;
Song, Li ;
Ma, Ding ;
Wang, Yun ;
Alshareef, Husam N. ;
He, Jr-Hau .
ADVANCED MATERIALS, 2019, 31 (48)
[76]  
Reimer L., 1998, SCAN ELECTRON MICROS, V2nd
[77]   In situ atomistic insight into the growth mechanisms of single layer 2D transition metal carbides [J].
Sang, Xiahan ;
Xie, Yu ;
Yilmaz, Dundar E. ;
Lotfi, Roghayyeh ;
Alhabeb, Mohamed ;
Ostadhossein, Alireza ;
Anasori, Babak ;
Sun, Weiwei ;
Li, Xufan ;
Xiao, Kai ;
Kent, Paul R. C. ;
van Duin, Adri C. T. ;
Gogotsi, Yury ;
Unocic, Raymond R. .
NATURE COMMUNICATIONS, 2018, 9
[78]   Atomic Defects in Monolayer Titanium Carbide (Ti3C2Tx) MXene [J].
Sang, Xiahan ;
Xie, Yu ;
Lin, Ming-Wei ;
Alhabeb, Mohamed ;
Van Aken, Katherine L. ;
Gogotsi, Yury ;
Kent, Paul R. C. ;
Xiao, Kai ;
Unocic, Raymond R. .
ACS NANO, 2016, 10 (10) :9193-9200
[79]   High-Temperature Behavior and Surface Chemistry of Carbide MXenes Studied by Thermal Analysis [J].
Seredych, Mykola ;
Shuck, Christopher Eugene ;
Pinto, David ;
Alhabeb, Mohamed ;
Precetti, Eliot ;
Deysher, Grayson ;
Anasori, Babak ;
Kurra, Narendra ;
Gogotsi, Yury .
CHEMISTRY OF MATERIALS, 2019, 31 (09) :3324-3332
[80]   Rational design of porous nitrogen-doped Ti3C2 MXene as a multifunctional electrocatalyst for Li-S chemistry [J].
Song, Yingze ;
Sun, Zhongti ;
Fan, Zhaodi ;
Cai, Wenlong ;
Shao, Yuanlong ;
Sheng, Guan ;
Wang, Menglei ;
Song, Lixian ;
Liu, Zhongfan ;
Zhang, Qiang ;
Sun, Jingyu .
NANO ENERGY, 2020, 70