Self-diffusion of Pd, Cu and Ni in Pd-based, equilibrium melts

被引:26
作者
Griesche, Axel
Macht, Michael-Peter
Suzuki, Shinsuke
Kraatz, Kurt-Helmut
Frohberg, Gunter
机构
[1] Hahn Meitner Inst Berlin GmbH, Dept Mat, D-14109 Berlin, Germany
[2] Tech Univ Berlin, Inst Mat Sci & Technol, Dept Met Phys, D-10623 Berlin, Germany
关键词
bulk amorphous materials; metallic glasses; liquids; diffusion in liquids; microgravity;
D O I
10.1016/j.scriptamat.2007.05.027
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Self-diffusion of Pd-108, Cu-65 and Ni-62 in molten Pd40Cu30Ni10P20 and of Pd-108 and Ni-62 in molten Pd40Ni40P20 has been measured by means of capillary techniques between 873 and 1073 K with and without influence of gravity. The diffusion coefficients are similar for all elements in the respective alloys and show the temperature dependence of diffusion of the mode-coupling theory. The results are discussed with respect to structural models of Pd-based bulk amorphous alloys. (c) 2007 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:477 / 480
页数:4
相关论文
共 23 条
[11]   A hard-sphere model in analytic form for atomic transport properties of liquid metals [J].
Itami, T ;
Sugimura, K .
PHYSICS AND CHEMISTRY OF LIQUIDS, 1995, 29 (01) :31-41
[12]   Investigation of specific volume of glass-forming Pd-Cu-Ni-P alloy in the liquid, vitreous and crystalline state [J].
Lu, IR ;
Görler, GP ;
Fecht, HJ ;
Willnecker, R .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 312-14 :547-551
[13]   Structural behavior of Pd40Cu30Ni10P20 bulk metallic glass below and above the glass transition [J].
Mattern, N ;
Hermann, H ;
Roth, S ;
Sakowski, J ;
Macht, MP ;
Jovari, P ;
Jiang, JZ .
APPLIED PHYSICS LETTERS, 2003, 82 (16) :2589-2591
[14]   Structural behavior of Zr52Ti5Cu18Ni15Al10 bulk metallic glass at high temperatures [J].
Mattern, N ;
Eckert, J ;
Kühn, U ;
Hermann, H ;
Sakowski, J ;
Herms, G ;
Neuefeind, J .
APPLIED PHYSICS LETTERS, 2002, 80 (24) :4525-4527
[15]  
Meyer A, 2002, PHYS REV B, V66, DOI 10.1103/PhysRevB.66.134205
[16]   Fast diffusion in ZrTiCuNiBe melts [J].
Meyer, A ;
Petry, W ;
Koza, M ;
Macht, MP .
APPLIED PHYSICS LETTERS, 2003, 83 (19) :3894-3896
[17]  
Nakajima H, 1999, JAPAN INSTITUTE OF METALS, PROCEEDINGS, VOL 12, (JIMIC-3), PTS 1 AND 2, P441
[18]   Structural study of Pd-based amorphous alloys with wide supercooled liquid region by anomalous X-ray scattering [J].
Park, C ;
Saito, M ;
Waseda, Y ;
Nishiyama, N ;
Inoue, A .
MATERIALS TRANSACTIONS JIM, 1999, 40 (06) :491-497
[19]   Viscoelasticity and viscosity of Pd-Ni-Cu-P bulk metallic glasses [J].
Pelletier, JM ;
Van de Moortèle, B ;
Lu, IR .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2002, 336 (1-2) :190-195
[20]   Shear Cell Development for Diffusion Experiments in Foton-Satellite Missions and on the Ground with Consideration of Shear-Induced Convection [J].
Suzuki, Shinsuke ;
Kraatz, Kurt-Helmut ;
Griesche, Axel ;
Frohberg, Guenter .
MICROGRAVITY SCIENCE AND TECHNOLOGY, 2005, 16 (1-4) :127-132